Water absorption and moisture permeation properties of chitosan/poly(acrylamide-co-itaconic acid) IPC films
•Cationic polymer Chitosan forms interpolyelectrolyte complex with anionic poly(AAm-co-IA).•These films show excellent pH dependent swelling behavior.•The water vapor permeation rate (WVPR) of these films fall within the prescribed range of normal wound. In this work, aqueous solutions of chitosan (...
Gespeichert in:
| Veröffentlicht in: | International journal of biological macromolecules 2016-03, Vol.84, p.1-9 |
|---|---|
| Hauptverfasser: | , , |
| Format: | Artikel |
| Sprache: | eng |
| Schlagworte: | |
| Online-Zugang: | Volltext |
| Tags: |
Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
|
| container_end_page | 9 |
|---|---|
| container_issue | |
| container_start_page | 1 |
| container_title | International journal of biological macromolecules |
| container_volume | 84 |
| creator | Bajpai, M. Bajpai, S.K. Jyotishi, Pooja |
| description | •Cationic polymer Chitosan forms interpolyelectrolyte complex with anionic poly(AAm-co-IA).•These films show excellent pH dependent swelling behavior.•The water vapor permeation rate (WVPR) of these films fall within the prescribed range of normal wound.
In this work, aqueous solutions of chitosan (Ch) and [poly(acrylamide(AAm)-co-itaconicacid(IA)] have been mixed to yield Ch/poly(AAm-co-IA) Inter-polyelectrolyte complex (IPC) films. The films were characterized by FTIR, X-ray diffraction (XRD) and thermo gravimetric analysis (TGA). There was remarkable increase in the crystalline nature of IPC films. The films were investigated for their water absorption capacity in the physiological fluid (PF) of pH 7.4 at 37°C. The amount of IA present in the film forming solutions affected the water absorption behavior of the resulting films. The dynamic water uptake data were interpreted by various kinetic models. The effect of pH on the swelling ratio (SR) indicated that the films showed highest swelling in lower as well as higher pH media. The water vapor transmission rates (WVTR) were obtained in the range of 6000–6645g/m2/day. |
| doi_str_mv | 10.1016/j.ijbiomac.2015.11.088 |
| format | Article |
| fullrecord | <record><control><sourceid>proquest_cross</sourceid><recordid>TN_cdi_proquest_miscellaneous_1760888597</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><els_id>S0141813015301859</els_id><sourcerecordid>1760888597</sourcerecordid><originalsourceid>FETCH-LOGICAL-c368t-d91dc15303bdf2485c7fe0bcc259aab348afdb7dc932adff5dd7a2f058beafb43</originalsourceid><addsrcrecordid>eNqFkE9v1DAQxS1ERZfCV6h8LIekdrJOnBtoVaBSJTi06tGajMfCSxIH24u03x6XbblyGs3Te_Pnx9ilFLUUsrve134_-jAD1o2QqpayFlq_Yhup-6ESQrSv2UbIray0bMU5e5vSvqidkvoNO2-6Tumm0Rv28xEyRQ5jCnHNPiwcFsvn4FM-ROIrxZngr77GULrsKfHgOP7wOSRYrtcwHa8A43GC2VuqMFQ-A4bFIwf09gO__b7jzk9zesfOHEyJ3j_XC_bw-eZ-97W6-_bldvfprsK207myg7QoVSva0bpmqxX2jsSI2KgBYGy3Gpwde4tD24B1TlnbQ-OE0iOBG7ftBbs6zS0n_zpQymb2CWmaYKFwSEb2XWGl1dAXa3eyYgwpRXJmjX6GeDRSmCfQZm9eQJsn0EZKU8IlePm84zDOZP_FXsgWw8eTgcqnvz1Fk9DTgmR9JMzGBv-_HX8AcKOVyA</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>1760888597</pqid></control><display><type>article</type><title>Water absorption and moisture permeation properties of chitosan/poly(acrylamide-co-itaconic acid) IPC films</title><source>Elsevier ScienceDirect Journals Complete - AutoHoldings</source><source>MEDLINE</source><creator>Bajpai, M. ; Bajpai, S.K. ; Jyotishi, Pooja</creator><creatorcontrib>Bajpai, M. ; Bajpai, S.K. ; Jyotishi, Pooja</creatorcontrib><description>•Cationic polymer Chitosan forms interpolyelectrolyte complex with anionic poly(AAm-co-IA).•These films show excellent pH dependent swelling behavior.•The water vapor permeation rate (WVPR) of these films fall within the prescribed range of normal wound.
In this work, aqueous solutions of chitosan (Ch) and [poly(acrylamide(AAm)-co-itaconicacid(IA)] have been mixed to yield Ch/poly(AAm-co-IA) Inter-polyelectrolyte complex (IPC) films. The films were characterized by FTIR, X-ray diffraction (XRD) and thermo gravimetric analysis (TGA). There was remarkable increase in the crystalline nature of IPC films. The films were investigated for their water absorption capacity in the physiological fluid (PF) of pH 7.4 at 37°C. The amount of IA present in the film forming solutions affected the water absorption behavior of the resulting films. The dynamic water uptake data were interpreted by various kinetic models. The effect of pH on the swelling ratio (SR) indicated that the films showed highest swelling in lower as well as higher pH media. The water vapor transmission rates (WVTR) were obtained in the range of 6000–6645g/m2/day.</description><identifier>ISSN: 0141-8130</identifier><identifier>EISSN: 1879-0003</identifier><identifier>DOI: 10.1016/j.ijbiomac.2015.11.088</identifier><identifier>PMID: 26658228</identifier><language>eng</language><publisher>Netherlands: Elsevier B.V</publisher><subject>Acrylic Resins - chemistry ; Adsorption ; Chitosan - chemistry ; Hydrogels ; Hydrogels - chemistry ; Hydrogen-Ion Concentration ; Molecular Weight ; Polyelectrolyte complex films ; Polymers ; Solubility ; Spectroscopy, Fourier Transform Infrared ; Succinates - chemistry ; Swelling ; Water - chemistry ; Water vapor transmission rate ; X-Ray Diffraction</subject><ispartof>International journal of biological macromolecules, 2016-03, Vol.84, p.1-9</ispartof><rights>2015 Elsevier B.V.</rights><rights>Copyright © 2015 Elsevier B.V. All rights reserved.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c368t-d91dc15303bdf2485c7fe0bcc259aab348afdb7dc932adff5dd7a2f058beafb43</citedby><cites>FETCH-LOGICAL-c368t-d91dc15303bdf2485c7fe0bcc259aab348afdb7dc932adff5dd7a2f058beafb43</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktohtml>$$Uhttps://dx.doi.org/10.1016/j.ijbiomac.2015.11.088$$EHTML$$P50$$Gelsevier$$H</linktohtml><link.rule.ids>314,780,784,3549,27923,27924,45994</link.rule.ids><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/26658228$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>Bajpai, M.</creatorcontrib><creatorcontrib>Bajpai, S.K.</creatorcontrib><creatorcontrib>Jyotishi, Pooja</creatorcontrib><title>Water absorption and moisture permeation properties of chitosan/poly(acrylamide-co-itaconic acid) IPC films</title><title>International journal of biological macromolecules</title><addtitle>Int J Biol Macromol</addtitle><description>•Cationic polymer Chitosan forms interpolyelectrolyte complex with anionic poly(AAm-co-IA).•These films show excellent pH dependent swelling behavior.•The water vapor permeation rate (WVPR) of these films fall within the prescribed range of normal wound.
In this work, aqueous solutions of chitosan (Ch) and [poly(acrylamide(AAm)-co-itaconicacid(IA)] have been mixed to yield Ch/poly(AAm-co-IA) Inter-polyelectrolyte complex (IPC) films. The films were characterized by FTIR, X-ray diffraction (XRD) and thermo gravimetric analysis (TGA). There was remarkable increase in the crystalline nature of IPC films. The films were investigated for their water absorption capacity in the physiological fluid (PF) of pH 7.4 at 37°C. The amount of IA present in the film forming solutions affected the water absorption behavior of the resulting films. The dynamic water uptake data were interpreted by various kinetic models. The effect of pH on the swelling ratio (SR) indicated that the films showed highest swelling in lower as well as higher pH media. The water vapor transmission rates (WVTR) were obtained in the range of 6000–6645g/m2/day.</description><subject>Acrylic Resins - chemistry</subject><subject>Adsorption</subject><subject>Chitosan - chemistry</subject><subject>Hydrogels</subject><subject>Hydrogels - chemistry</subject><subject>Hydrogen-Ion Concentration</subject><subject>Molecular Weight</subject><subject>Polyelectrolyte complex films</subject><subject>Polymers</subject><subject>Solubility</subject><subject>Spectroscopy, Fourier Transform Infrared</subject><subject>Succinates - chemistry</subject><subject>Swelling</subject><subject>Water - chemistry</subject><subject>Water vapor transmission rate</subject><subject>X-Ray Diffraction</subject><issn>0141-8130</issn><issn>1879-0003</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2016</creationdate><recordtype>article</recordtype><sourceid>EIF</sourceid><recordid>eNqFkE9v1DAQxS1ERZfCV6h8LIekdrJOnBtoVaBSJTi06tGajMfCSxIH24u03x6XbblyGs3Te_Pnx9ilFLUUsrve134_-jAD1o2QqpayFlq_Yhup-6ESQrSv2UbIray0bMU5e5vSvqidkvoNO2-6Tumm0Rv28xEyRQ5jCnHNPiwcFsvn4FM-ROIrxZngr77GULrsKfHgOP7wOSRYrtcwHa8A43GC2VuqMFQ-A4bFIwf09gO__b7jzk9zesfOHEyJ3j_XC_bw-eZ-97W6-_bldvfprsK207myg7QoVSva0bpmqxX2jsSI2KgBYGy3Gpwde4tD24B1TlnbQ-OE0iOBG7ftBbs6zS0n_zpQymb2CWmaYKFwSEb2XWGl1dAXa3eyYgwpRXJmjX6GeDRSmCfQZm9eQJsn0EZKU8IlePm84zDOZP_FXsgWw8eTgcqnvz1Fk9DTgmR9JMzGBv-_HX8AcKOVyA</recordid><startdate>201603</startdate><enddate>201603</enddate><creator>Bajpai, M.</creator><creator>Bajpai, S.K.</creator><creator>Jyotishi, Pooja</creator><general>Elsevier B.V</general><scope>CGR</scope><scope>CUY</scope><scope>CVF</scope><scope>ECM</scope><scope>EIF</scope><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7X8</scope></search><sort><creationdate>201603</creationdate><title>Water absorption and moisture permeation properties of chitosan/poly(acrylamide-co-itaconic acid) IPC films</title><author>Bajpai, M. ; Bajpai, S.K. ; Jyotishi, Pooja</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c368t-d91dc15303bdf2485c7fe0bcc259aab348afdb7dc932adff5dd7a2f058beafb43</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2016</creationdate><topic>Acrylic Resins - chemistry</topic><topic>Adsorption</topic><topic>Chitosan - chemistry</topic><topic>Hydrogels</topic><topic>Hydrogels - chemistry</topic><topic>Hydrogen-Ion Concentration</topic><topic>Molecular Weight</topic><topic>Polyelectrolyte complex films</topic><topic>Polymers</topic><topic>Solubility</topic><topic>Spectroscopy, Fourier Transform Infrared</topic><topic>Succinates - chemistry</topic><topic>Swelling</topic><topic>Water - chemistry</topic><topic>Water vapor transmission rate</topic><topic>X-Ray Diffraction</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Bajpai, M.</creatorcontrib><creatorcontrib>Bajpai, S.K.</creatorcontrib><creatorcontrib>Jyotishi, Pooja</creatorcontrib><collection>Medline</collection><collection>MEDLINE</collection><collection>MEDLINE (Ovid)</collection><collection>MEDLINE</collection><collection>MEDLINE</collection><collection>PubMed</collection><collection>CrossRef</collection><collection>MEDLINE - Academic</collection><jtitle>International journal of biological macromolecules</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Bajpai, M.</au><au>Bajpai, S.K.</au><au>Jyotishi, Pooja</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Water absorption and moisture permeation properties of chitosan/poly(acrylamide-co-itaconic acid) IPC films</atitle><jtitle>International journal of biological macromolecules</jtitle><addtitle>Int J Biol Macromol</addtitle><date>2016-03</date><risdate>2016</risdate><volume>84</volume><spage>1</spage><epage>9</epage><pages>1-9</pages><issn>0141-8130</issn><eissn>1879-0003</eissn><abstract>•Cationic polymer Chitosan forms interpolyelectrolyte complex with anionic poly(AAm-co-IA).•These films show excellent pH dependent swelling behavior.•The water vapor permeation rate (WVPR) of these films fall within the prescribed range of normal wound.
In this work, aqueous solutions of chitosan (Ch) and [poly(acrylamide(AAm)-co-itaconicacid(IA)] have been mixed to yield Ch/poly(AAm-co-IA) Inter-polyelectrolyte complex (IPC) films. The films were characterized by FTIR, X-ray diffraction (XRD) and thermo gravimetric analysis (TGA). There was remarkable increase in the crystalline nature of IPC films. The films were investigated for their water absorption capacity in the physiological fluid (PF) of pH 7.4 at 37°C. The amount of IA present in the film forming solutions affected the water absorption behavior of the resulting films. The dynamic water uptake data were interpreted by various kinetic models. The effect of pH on the swelling ratio (SR) indicated that the films showed highest swelling in lower as well as higher pH media. The water vapor transmission rates (WVTR) were obtained in the range of 6000–6645g/m2/day.</abstract><cop>Netherlands</cop><pub>Elsevier B.V</pub><pmid>26658228</pmid><doi>10.1016/j.ijbiomac.2015.11.088</doi><tpages>9</tpages></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 0141-8130 |
| ispartof | International journal of biological macromolecules, 2016-03, Vol.84, p.1-9 |
| issn | 0141-8130 1879-0003 |
| language | eng |
| recordid | cdi_proquest_miscellaneous_1760888597 |
| source | Elsevier ScienceDirect Journals Complete - AutoHoldings; MEDLINE |
| subjects | Acrylic Resins - chemistry Adsorption Chitosan - chemistry Hydrogels Hydrogels - chemistry Hydrogen-Ion Concentration Molecular Weight Polyelectrolyte complex films Polymers Solubility Spectroscopy, Fourier Transform Infrared Succinates - chemistry Swelling Water - chemistry Water vapor transmission rate X-Ray Diffraction |
| title | Water absorption and moisture permeation properties of chitosan/poly(acrylamide-co-itaconic acid) IPC films |
| url | https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2025-01-09T05%3A57%3A06IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-proquest_cross&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Water%20absorption%20and%20moisture%20permeation%20properties%20of%20chitosan/poly(acrylamide-co-itaconic%20acid)%20IPC%20films&rft.jtitle=International%20journal%20of%20biological%20macromolecules&rft.au=Bajpai,%20M.&rft.date=2016-03&rft.volume=84&rft.spage=1&rft.epage=9&rft.pages=1-9&rft.issn=0141-8130&rft.eissn=1879-0003&rft_id=info:doi/10.1016/j.ijbiomac.2015.11.088&rft_dat=%3Cproquest_cross%3E1760888597%3C/proquest_cross%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_pqid=1760888597&rft_id=info:pmid/26658228&rft_els_id=S0141813015301859&rfr_iscdi=true |