Heterometallic Rings: Their Physics and use as Supramolecular Building Blocks

An enormous family of heterometallic rings has been made. The first were Cr7M rings where M=NiII, ZnII, MnII, and rings have been made with as many as fourteen metal centers in the cyclic structure. They are bridged externally by carboxylates, and internally by fluorides or a penta‐deprotonated poly...

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Veröffentlicht in:	Angewandte Chemie International Edition 2015-11, Vol.54 (48), p.14244-14269
Hauptverfasser:	McInnes, Eric J. L., Timco, Grigore A., Whitehead, George F. S., Winpenny, Richard E. P.
Format:	Artikel
Sprache:	eng
Schlagworte:	Alkali metals Ammonium carboxylate clusters Carboxylates Coordination compounds Electron paramagnetic resonance Electron spin resonance Fluorides heterometallic rings Inelastic scattering Magnetic measurement Magnetic resonance spectroscopy Magnetism metallocycles molecular magnets Neutron diffraction Neutron scattering Neutrons NMR NMR spectroscopy Nuclear magnetic resonance Resonance scattering Rotaxanes Single crystals Spectroscopic analysis Spectroscopy Spectrum analysis supramolecular chemistry
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