Synthesis of a Neutral Mixed-Valence Diferrocenyl Carborane for Molecular Quantum-Dot Cellular Automata Applications

The preparation of 7‐Fc+‐8‐Fc‐7,8‐nido‐[C2B9H10]− (Fc+FcC2B9−) demonstrates the successful incorporation of a carborane cage as an internal counteranion bridging between ferrocene and ferrocenium units. This neutral mixed‐valence FeII/FeIII complex overcomes the proximal electronic bias imposed by e...

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Veröffentlicht in:	Angewandte Chemie International Edition 2015-12, Vol.54 (51), p.15448-15451
Hauptverfasser:	Christie, John A., Forrest, Ryan P., Corcelli, Steven A., Wasio, Natalie A., Quardokus, Rebecca C., Brown, Ryan, Kandel, S. Alex, Lu, Yuhui, Lent, Craig S., Henderson, Kenneth W.
Format:	Artikel
Sprache:	eng
Schlagworte:	Automata theory Carborane carboranes Cellular automata Computer applications Electron transfer mixed-valence compounds Molecular machines QCA Scanning tunneling microscopy STM Switches zwitterions
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