Hydrophilic Nitrogen and Sulfur Co-doped Molybdenum Carbide Nanosheets for Electrochemical Hydrogen Evolution

Hydrophilic Nitrogen and Sulfur Co-doped Molybdenum Carbide Nanosheets for Electrochemical Hydrogen Evolution

Nitrogen and sulfur dual‐doped Mo2C nanosheets provide low operating potential (−86 mV for driving 10 mA cm−2 of current density). Co‐doping of N and S heteroatoms can improve the wetting property of the Mo2C electrocatalyst in aqueous solution and induce synergistic effects via σ‐donation and π‐bac...

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Veröffentlicht in:Small (Weinheim an der Bergstrasse, Germany) Germany), 2015-12, Vol.11 (47), p.6278-6284
Hauptverfasser: Ang, Huixiang, Tan, Hui Teng, Luo, Zhi Min, Zhang, Yu, Guo, Yuan Yuan, Guo, Guilue, Zhang, Hua, Yan, Qingyu
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Sprache:eng
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hydrogen evolution reaction
molybdenum carbide
Nanotechnology
nitrogen/sulfur
synergistic effects
wetting
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container_end_page 6284
container_issue 47
container_start_page 6278
container_title Small (Weinheim an der Bergstrasse, Germany)
container_volume 11
creator Ang, Huixiang
Tan, Hui Teng
Luo, Zhi Min
Zhang, Yu
Guo, Yuan Yuan
Guo, Guilue
Zhang, Hua
Yan, Qingyu
description Nitrogen and sulfur dual‐doped Mo2C nanosheets provide low operating potential (−86 mV for driving 10 mA cm−2 of current density). Co‐doping of N and S heteroatoms can improve the wetting property of the Mo2C electrocatalyst in aqueous solution and induce synergistic effects via σ‐donation and π‐back donation with hydronium cation.
doi_str_mv 10.1002/smll.201502106
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subjects hydrogen evolution reaction
molybdenum carbide
Nanotechnology
nitrogen/sulfur
synergistic effects
wetting
title Hydrophilic Nitrogen and Sulfur Co-doped Molybdenum Carbide Nanosheets for Electrochemical Hydrogen Evolution
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