An Electron-Deficient Building Block Based on the B←N Unit: An Electron Acceptor for All-Polymer Solar Cells
A double B←N bridged bipyridyl (BNBP) is a novel electron‐deficient building block for polymer electron acceptors in all‐polymer solar cells. The B←N bridging units endow BNBP with fixed planar configuration and low‐lying LUMO/HOMO energy levels. As a result, the polymer based on BNBP units (P‐BNBP‐...
Gespeichert in:
| Veröffentlicht in: | Angewandte Chemie International Edition 2016-01, Vol.55 (4), p.1436-1440 |
|---|---|
| Hauptverfasser: | , , , , , |
| Format: | Artikel |
| Sprache: | eng |
| Schlagworte: | |
| Online-Zugang: | Volltext |
| Tags: |
Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
|
| container_end_page | 1440 |
|---|---|
| container_issue | 4 |
| container_start_page | 1436 |
| container_title | Angewandte Chemie International Edition |
| container_volume | 55 |
| creator | Dou, Chuandong Long, Xiaojing Ding, Zicheng Xie, Zhiyuan Liu, Jun Wang, Lixiang |
| description | A double B←N bridged bipyridyl (BNBP) is a novel electron‐deficient building block for polymer electron acceptors in all‐polymer solar cells. The B←N bridging units endow BNBP with fixed planar configuration and low‐lying LUMO/HOMO energy levels. As a result, the polymer based on BNBP units (P‐BNBP‐T) exhibits high electron mobility, low‐lying LUMO/HOMO energy levels, and strong absorbance in the visible region, which is desirable for polymer electron acceptors. Preliminary all‐polymer solar cell (all‐PSC) devices with P‐BNBP‐T as the electron acceptor and PTB7 as the electron donor exhibit a power conversion efficiency (PCE) of 3.38 %, which is among the highest values of all‐PSCs with PTB7 as the electron donor.
A bridge too far: An electron‐deficient building block comprises a double B←N bridged bipyridyl (BNBP) moiety. The polymer constructed from the BNBP units exhibits high electron mobility, low‐lying LUMO/HOMO energy levels, and strong absorbance in the visible range, and shows excellent device performance as polymer electron acceptor for all‐polymer solar cells. |
| doi_str_mv | 10.1002/anie.201508482 |
| format | Article |
| fullrecord | <record><control><sourceid>proquest_cross</sourceid><recordid>TN_cdi_proquest_miscellaneous_1760861389</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>1760861389</sourcerecordid><originalsourceid>FETCH-LOGICAL-c6122-37e37e4e3ab364148ed169676b5d429fea94d654c73c10ce5ce7b805f406840d3</originalsourceid><addsrcrecordid>eNqFkc1uEzEUhUcIREthyxJZYtPNBHv8O-wmaWgLVUCCCnbWxHMH3Dp2sGdE8wJd84w8CY5SoooFSPfq3sV3jo50iuI5wROCcfWq9RYmFSYcK6aqB8Uh4RUpqZT0Yf4ZpaVUnBwUT1K6yrxSWDwuDiohBOWEHha-8WjuwAwx-PIEemss-AFNR-s667-iqQvmGk3bBB0KHg3fAE1_3f5coEtvh9fonho1xsB6CBH1eRvnyg_BbVYQ0cfg2ohm4Fx6WjzqW5fg2d09Ki7fzD_NzsqL96fns-aiNIJUVc4PeRjQdkkFI0xBR0QtpFjyjlV1D23NOsGZkdQQbIAbkEuFec-wUAx39Kg43vmuY_g-Qhr0yiaTE7Qewpg0kQIrQaiqM_ryL_QqjNHndJrUWAhJBFf_pCSXEisqttRkR5kYUorQ63W0qzZuNMF625fe9qX3fWXBizvbcbmCbo__KSgD9Q74YR1s_mOnm8X5_L55udPaNMDNXtvGay0klVx_XpzqsxPy9suC1Pod_Q12G65A</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>1757708368</pqid></control><display><type>article</type><title>An Electron-Deficient Building Block Based on the B←N Unit: An Electron Acceptor for All-Polymer Solar Cells</title><source>Wiley Journals</source><creator>Dou, Chuandong ; Long, Xiaojing ; Ding, Zicheng ; Xie, Zhiyuan ; Liu, Jun ; Wang, Lixiang</creator><creatorcontrib>Dou, Chuandong ; Long, Xiaojing ; Ding, Zicheng ; Xie, Zhiyuan ; Liu, Jun ; Wang, Lixiang</creatorcontrib><description>A double B←N bridged bipyridyl (BNBP) is a novel electron‐deficient building block for polymer electron acceptors in all‐polymer solar cells. The B←N bridging units endow BNBP with fixed planar configuration and low‐lying LUMO/HOMO energy levels. As a result, the polymer based on BNBP units (P‐BNBP‐T) exhibits high electron mobility, low‐lying LUMO/HOMO energy levels, and strong absorbance in the visible region, which is desirable for polymer electron acceptors. Preliminary all‐polymer solar cell (all‐PSC) devices with P‐BNBP‐T as the electron acceptor and PTB7 as the electron donor exhibit a power conversion efficiency (PCE) of 3.38 %, which is among the highest values of all‐PSCs with PTB7 as the electron donor.
A bridge too far: An electron‐deficient building block comprises a double B←N bridged bipyridyl (BNBP) moiety. The polymer constructed from the BNBP units exhibits high electron mobility, low‐lying LUMO/HOMO energy levels, and strong absorbance in the visible range, and shows excellent device performance as polymer electron acceptor for all‐polymer solar cells.</description><edition>International ed. in English</edition><identifier>ISSN: 1433-7851</identifier><identifier>EISSN: 1521-3773</identifier><identifier>DOI: 10.1002/anie.201508482</identifier><identifier>PMID: 26663513</identifier><identifier>CODEN: ACIEAY</identifier><language>eng</language><publisher>Germany: Blackwell Publishing Ltd</publisher><subject>Absorbance ; B-N coordination ; boron ; electron acceptor ; Electron mobility ; Energy ; Energy conversion efficiency ; Energy levels ; Lymphocytes B ; Molecular orbitals ; Photovoltaic cells ; Polymers ; Solar cells</subject><ispartof>Angewandte Chemie International Edition, 2016-01, Vol.55 (4), p.1436-1440</ispartof><rights>2016 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim</rights><rights>2016 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.</rights><rights>2016 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c6122-37e37e4e3ab364148ed169676b5d429fea94d654c73c10ce5ce7b805f406840d3</citedby><cites>FETCH-LOGICAL-c6122-37e37e4e3ab364148ed169676b5d429fea94d654c73c10ce5ce7b805f406840d3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://onlinelibrary.wiley.com/doi/pdf/10.1002%2Fanie.201508482$$EPDF$$P50$$Gwiley$$H</linktopdf><linktohtml>$$Uhttps://onlinelibrary.wiley.com/doi/full/10.1002%2Fanie.201508482$$EHTML$$P50$$Gwiley$$H</linktohtml><link.rule.ids>314,780,784,1417,27924,27925,45574,45575</link.rule.ids><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/26663513$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>Dou, Chuandong</creatorcontrib><creatorcontrib>Long, Xiaojing</creatorcontrib><creatorcontrib>Ding, Zicheng</creatorcontrib><creatorcontrib>Xie, Zhiyuan</creatorcontrib><creatorcontrib>Liu, Jun</creatorcontrib><creatorcontrib>Wang, Lixiang</creatorcontrib><title>An Electron-Deficient Building Block Based on the B←N Unit: An Electron Acceptor for All-Polymer Solar Cells</title><title>Angewandte Chemie International Edition</title><addtitle>Angew. Chem. Int. Ed</addtitle><description>A double B←N bridged bipyridyl (BNBP) is a novel electron‐deficient building block for polymer electron acceptors in all‐polymer solar cells. The B←N bridging units endow BNBP with fixed planar configuration and low‐lying LUMO/HOMO energy levels. As a result, the polymer based on BNBP units (P‐BNBP‐T) exhibits high electron mobility, low‐lying LUMO/HOMO energy levels, and strong absorbance in the visible region, which is desirable for polymer electron acceptors. Preliminary all‐polymer solar cell (all‐PSC) devices with P‐BNBP‐T as the electron acceptor and PTB7 as the electron donor exhibit a power conversion efficiency (PCE) of 3.38 %, which is among the highest values of all‐PSCs with PTB7 as the electron donor.
A bridge too far: An electron‐deficient building block comprises a double B←N bridged bipyridyl (BNBP) moiety. The polymer constructed from the BNBP units exhibits high electron mobility, low‐lying LUMO/HOMO energy levels, and strong absorbance in the visible range, and shows excellent device performance as polymer electron acceptor for all‐polymer solar cells.</description><subject>Absorbance</subject><subject>B-N coordination</subject><subject>boron</subject><subject>electron acceptor</subject><subject>Electron mobility</subject><subject>Energy</subject><subject>Energy conversion efficiency</subject><subject>Energy levels</subject><subject>Lymphocytes B</subject><subject>Molecular orbitals</subject><subject>Photovoltaic cells</subject><subject>Polymers</subject><subject>Solar cells</subject><issn>1433-7851</issn><issn>1521-3773</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2016</creationdate><recordtype>article</recordtype><recordid>eNqFkc1uEzEUhUcIREthyxJZYtPNBHv8O-wmaWgLVUCCCnbWxHMH3Dp2sGdE8wJd84w8CY5SoooFSPfq3sV3jo50iuI5wROCcfWq9RYmFSYcK6aqB8Uh4RUpqZT0Yf4ZpaVUnBwUT1K6yrxSWDwuDiohBOWEHha-8WjuwAwx-PIEemss-AFNR-s667-iqQvmGk3bBB0KHg3fAE1_3f5coEtvh9fonho1xsB6CBH1eRvnyg_BbVYQ0cfg2ohm4Fx6WjzqW5fg2d09Ki7fzD_NzsqL96fns-aiNIJUVc4PeRjQdkkFI0xBR0QtpFjyjlV1D23NOsGZkdQQbIAbkEuFec-wUAx39Kg43vmuY_g-Qhr0yiaTE7Qewpg0kQIrQaiqM_ryL_QqjNHndJrUWAhJBFf_pCSXEisqttRkR5kYUorQ63W0qzZuNMF625fe9qX3fWXBizvbcbmCbo__KSgD9Q74YR1s_mOnm8X5_L55udPaNMDNXtvGay0klVx_XpzqsxPy9suC1Pod_Q12G65A</recordid><startdate>20160122</startdate><enddate>20160122</enddate><creator>Dou, Chuandong</creator><creator>Long, Xiaojing</creator><creator>Ding, Zicheng</creator><creator>Xie, Zhiyuan</creator><creator>Liu, Jun</creator><creator>Wang, Lixiang</creator><general>Blackwell Publishing Ltd</general><general>Wiley Subscription Services, Inc</general><scope>BSCLL</scope><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7TM</scope><scope>K9.</scope><scope>7X8</scope></search><sort><creationdate>20160122</creationdate><title>An Electron-Deficient Building Block Based on the B←N Unit: An Electron Acceptor for All-Polymer Solar Cells</title><author>Dou, Chuandong ; Long, Xiaojing ; Ding, Zicheng ; Xie, Zhiyuan ; Liu, Jun ; Wang, Lixiang</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c6122-37e37e4e3ab364148ed169676b5d429fea94d654c73c10ce5ce7b805f406840d3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2016</creationdate><topic>Absorbance</topic><topic>B-N coordination</topic><topic>boron</topic><topic>electron acceptor</topic><topic>Electron mobility</topic><topic>Energy</topic><topic>Energy conversion efficiency</topic><topic>Energy levels</topic><topic>Lymphocytes B</topic><topic>Molecular orbitals</topic><topic>Photovoltaic cells</topic><topic>Polymers</topic><topic>Solar cells</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Dou, Chuandong</creatorcontrib><creatorcontrib>Long, Xiaojing</creatorcontrib><creatorcontrib>Ding, Zicheng</creatorcontrib><creatorcontrib>Xie, Zhiyuan</creatorcontrib><creatorcontrib>Liu, Jun</creatorcontrib><creatorcontrib>Wang, Lixiang</creatorcontrib><collection>Istex</collection><collection>PubMed</collection><collection>CrossRef</collection><collection>Nucleic Acids Abstracts</collection><collection>ProQuest Health & Medical Complete (Alumni)</collection><collection>MEDLINE - Academic</collection><jtitle>Angewandte Chemie International Edition</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Dou, Chuandong</au><au>Long, Xiaojing</au><au>Ding, Zicheng</au><au>Xie, Zhiyuan</au><au>Liu, Jun</au><au>Wang, Lixiang</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>An Electron-Deficient Building Block Based on the B←N Unit: An Electron Acceptor for All-Polymer Solar Cells</atitle><jtitle>Angewandte Chemie International Edition</jtitle><addtitle>Angew. Chem. Int. Ed</addtitle><date>2016-01-22</date><risdate>2016</risdate><volume>55</volume><issue>4</issue><spage>1436</spage><epage>1440</epage><pages>1436-1440</pages><issn>1433-7851</issn><eissn>1521-3773</eissn><coden>ACIEAY</coden><abstract>A double B←N bridged bipyridyl (BNBP) is a novel electron‐deficient building block for polymer electron acceptors in all‐polymer solar cells. The B←N bridging units endow BNBP with fixed planar configuration and low‐lying LUMO/HOMO energy levels. As a result, the polymer based on BNBP units (P‐BNBP‐T) exhibits high electron mobility, low‐lying LUMO/HOMO energy levels, and strong absorbance in the visible region, which is desirable for polymer electron acceptors. Preliminary all‐polymer solar cell (all‐PSC) devices with P‐BNBP‐T as the electron acceptor and PTB7 as the electron donor exhibit a power conversion efficiency (PCE) of 3.38 %, which is among the highest values of all‐PSCs with PTB7 as the electron donor.
A bridge too far: An electron‐deficient building block comprises a double B←N bridged bipyridyl (BNBP) moiety. The polymer constructed from the BNBP units exhibits high electron mobility, low‐lying LUMO/HOMO energy levels, and strong absorbance in the visible range, and shows excellent device performance as polymer electron acceptor for all‐polymer solar cells.</abstract><cop>Germany</cop><pub>Blackwell Publishing Ltd</pub><pmid>26663513</pmid><doi>10.1002/anie.201508482</doi><tpages>5</tpages><edition>International ed. in English</edition></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 1433-7851 |
| ispartof | Angewandte Chemie International Edition, 2016-01, Vol.55 (4), p.1436-1440 |
| issn | 1433-7851 1521-3773 |
| language | eng |
| recordid | cdi_proquest_miscellaneous_1760861389 |
| source | Wiley Journals |
| subjects | Absorbance B-N coordination boron electron acceptor Electron mobility Energy Energy conversion efficiency Energy levels Lymphocytes B Molecular orbitals Photovoltaic cells Polymers Solar cells |
| title | An Electron-Deficient Building Block Based on the B←N Unit: An Electron Acceptor for All-Polymer Solar Cells |
| url | https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2025-01-04T05%3A28%3A04IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-proquest_cross&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=An%20Electron-Deficient%20Building%20Block%20Based%20on%20the%20B%E2%86%90N%20Unit:%20An%20Electron%20Acceptor%20for%20All-Polymer%20Solar%20Cells&rft.jtitle=Angewandte%20Chemie%20International%20Edition&rft.au=Dou,%20Chuandong&rft.date=2016-01-22&rft.volume=55&rft.issue=4&rft.spage=1436&rft.epage=1440&rft.pages=1436-1440&rft.issn=1433-7851&rft.eissn=1521-3773&rft.coden=ACIEAY&rft_id=info:doi/10.1002/anie.201508482&rft_dat=%3Cproquest_cross%3E1760861389%3C/proquest_cross%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_pqid=1757708368&rft_id=info:pmid/26663513&rfr_iscdi=true |