Compressed Corannulene in a Molecular Cage

Self‐assembled coordination cages can be employed as a molecular press, where the bowl‐shaped guest corannulene (C20H10) is significantly flattened upon inclusion within the hydrophobic cavity. This is demonstrated by the pairwise inclusion of corannulene with naphthalene diimide as well as by the d...

Ausführliche Beschreibung

Bibliographische Detailangaben

Veröffentlicht in:	Angewandte Chemie International Edition 2016-01, Vol.55 (4), p.1561-1564
Hauptverfasser:	Schmidt, Bernd M., Osuga, Takafumi, Sawada, Tomohisa, Hoshino, Manabu, Fujita, Makoto
Format:	Artikel
Sprache:	eng
Schlagworte:	cage compounds Cages corannulenes Crystal structure Diimide Flattening Holes host-guest systems Hydrophobicity Naphthalene Single crystals supramolecular chemistry X ray analysis π interactions
Online-Zugang:	Volltext
Tags:	Tag hinzufügen Keine Tags, Fügen Sie den ersten Tag hinzu!