Self-assembled construction of a sheet-type coordination polymer bearing cationic M2L4 cages: creation of channel-like space for removal of ClO4(-) and NO3(-) from aqueous solutions

Self-assembled construction of a sheet-type coordination polymer bearing cationic M2L4 cages: creation of channel-like space for removal of ClO4(-) and NO3(-) from aqueous solutions

Treatment of CuCl2 with a bis-benzimidazole-type ligand, p-bbiteb, afforded a new 2D coordination polymer bearing cationic Cu2L4 cages on the sheet framework. The regular arrangement of the cages created channel-like space for anions. The compound removed ClO4(-) and NO3(-) from aqueous solutions by...

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Veröffentlicht in:Dalton transactions : an international journal of inorganic chemistry 2016-01, Vol.45 (3), p.894-898
Hauptverfasser: Sone, Eriko, Sato, Moeko, Yamanishi, Katsunori, Kamio, Chihiro, Takemoto, Hiroyuki, Kondo, Mitsuru
Format: Artikel
Sprache:eng
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Zusammenfassung:Treatment of CuCl2 with a bis-benzimidazole-type ligand, p-bbiteb, afforded a new 2D coordination polymer bearing cationic Cu2L4 cages on the sheet framework. The regular arrangement of the cages created channel-like space for anions. The compound removed ClO4(-) and NO3(-) from aqueous solutions by exchange with Cl(-) in the channels.
ISSN:1477-9234
DOI:10.1039/c5dt03602j