Cooperative reduction by Ln(2+) and Cp(-) ions: synthesis and properties of Sm, Eu, and Yb complexes with 3,6-di-tert-butyl-o-benzoquinone

The first examples of samarium, europium, and ytterbium complexes with 3,6-di-tert-butyl-o-benzoquinone(3,6-dbbq) in the form of catecholate have been obtained by reactions of the quinone with the corresponding lanthanocenes, [LnCp2*(thf)n] (n = 1 or 2) in solution. In the course of the reactions la...

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Veröffentlicht in:Dalton transactions : an international journal of inorganic chemistry 2016-01, Vol.45 (3), p.1269-1278
Hauptverfasser: Pushkarevsky, Nikolay A, Ogienko, Mikhail A, Smolentsev, Anton I, Novozhilov, Igor N, Witt, Alexander, Khusniyarov, Marat M, Cherkasov, Vladimir K, Konchenko, Sergey N
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Sprache:eng
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