Enhancement of the magnetic sensitivity of singlet to triplet transition in Fe-dopant Sr3(CrFe)2O8

Magnetizations of the Fe doped Sr3Cr2O8 single crystals Sr3Cr2−xFexO8 (x=0, 0.05 and 0.1) were investigated in the temperature ranging from 2 to 300K and the magnetic field ranging from 0 to 16T. Based on the Curie–Weiss law and the Bleaney–Bowers model, the low field magnetization behaviors were an...

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Veröffentlicht in:Journal of magnetism and magnetic materials 2013-10, Vol.344, p.85-88
Hauptverfasser: Chen, B.R., Xia, Z.C., Li, H.N., Xiao, L.X., Huang, J.W., Wu, Y.Y., Ouyang, Z.W., Jin, Z., Shi, L.R., Wei, M.
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container_issue
container_start_page 85
container_title Journal of magnetism and magnetic materials
container_volume 344
creator Chen, B.R.
Xia, Z.C.
Li, H.N.
Xiao, L.X.
Huang, J.W.
Wu, Y.Y.
Ouyang, Z.W.
Jin, Z.
Shi, L.R.
Wei, M.
description Magnetizations of the Fe doped Sr3Cr2O8 single crystals Sr3Cr2−xFexO8 (x=0, 0.05 and 0.1) were investigated in the temperature ranging from 2 to 300K and the magnetic field ranging from 0 to 16T. Based on the Curie–Weiss law and the Bleaney–Bowers model, the low field magnetization behaviors were analyzed. Experimental results show that the Fe5+ dopant has influence on the intradimer interaction J0, the interdimer interaction J', and the average change rate Δχ/ΔT of spin-dimer susceptibility χdimer of Sr3Cr2−xFexO8. Especially, in this spin-dimer system, the Fe5+ dopant can obviously enhance the magnetic sensitivity of singlet to triplet transition in Sr3Cr2O8. •Sr3Cr2−xFexO8 (x=0, 0.05 and 0.1) single crystals have been grown successfully.•Magnetization sharply change confirms Sr3Cr2−xFexO8 as a spin-1/2 antiferromagnet.•Fe5+ has influence on J0, J', Δχ/ΔT of spin-dimer susceptibility χdimer.•Fe5+ dopant enhances magnetic sensitivity of Sr3Cr2O8 from singlet to triplet.
doi_str_mv 10.1016/j.jmmm.2013.05.049
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Especially, in this spin-dimer system, the Fe5+ dopant can obviously enhance the magnetic sensitivity of singlet to triplet transition in Sr3Cr2O8. •Sr3Cr2−xFexO8 (x=0, 0.05 and 0.1) single crystals have been grown successfully.•Magnetization sharply change confirms Sr3Cr2−xFexO8 as a spin-1/2 antiferromagnet.•Fe5+ has influence on J0, J', Δχ/ΔT of spin-dimer susceptibility χdimer.•Fe5+ dopant enhances magnetic sensitivity of Sr3Cr2O8 from singlet to triplet.</description><identifier>ISSN: 0304-8853</identifier><identifier>DOI: 10.1016/j.jmmm.2013.05.049</identifier><identifier>CODEN: JMMMDC</identifier><language>eng</language><publisher>Amsterdam: Elsevier B.V</publisher><subject>Condensed matter: electronic structure, electrical, magnetic, and optical properties ; Curie-Weiss law ; Domain effects, magnetization curves, and hysteresis ; Dopants ; Exact sciences and technology ; Iron ; Magnetic fields ; Magnetic materials ; Magnetic permeability ; Magnetic properties and materials ; Magnetically ordered materials: other intrinsic properties ; Magnetism ; Magnetization ; Magnetization curves, magnetization reversal, hysteresis, barkhausen and related effects ; Physics ; Saturation moments and magnetic susceptibilities ; Single crystals ; Spin-dimer ; Transition</subject><ispartof>Journal of magnetism and magnetic materials, 2013-10, Vol.344, p.85-88</ispartof><rights>2013 Elsevier B.V.</rights><rights>2014 INIST-CNRS</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c396t-1463bd7694d904457edde17da43314332aabbe3a51c17a40dc2ced9d58d9e33d3</citedby><cites>FETCH-LOGICAL-c396t-1463bd7694d904457edde17da43314332aabbe3a51c17a40dc2ced9d58d9e33d3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktohtml>$$Uhttps://www.sciencedirect.com/science/article/pii/S0304885313003879$$EHTML$$P50$$Gelsevier$$H</linktohtml><link.rule.ids>314,776,780,3536,27903,27904,65309</link.rule.ids><backlink>$$Uhttp://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&amp;idt=27574205$$DView record in Pascal Francis$$Hfree_for_read</backlink></links><search><creatorcontrib>Chen, B.R.</creatorcontrib><creatorcontrib>Xia, Z.C.</creatorcontrib><creatorcontrib>Li, H.N.</creatorcontrib><creatorcontrib>Xiao, L.X.</creatorcontrib><creatorcontrib>Huang, J.W.</creatorcontrib><creatorcontrib>Wu, Y.Y.</creatorcontrib><creatorcontrib>Ouyang, Z.W.</creatorcontrib><creatorcontrib>Jin, Z.</creatorcontrib><creatorcontrib>Shi, L.R.</creatorcontrib><creatorcontrib>Wei, M.</creatorcontrib><title>Enhancement of the magnetic sensitivity of singlet to triplet transition in Fe-dopant Sr3(CrFe)2O8</title><title>Journal of magnetism and magnetic materials</title><description>Magnetizations of the Fe doped Sr3Cr2O8 single crystals Sr3Cr2−xFexO8 (x=0, 0.05 and 0.1) were investigated in the temperature ranging from 2 to 300K and the magnetic field ranging from 0 to 16T. 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Based on the Curie–Weiss law and the Bleaney–Bowers model, the low field magnetization behaviors were analyzed. Experimental results show that the Fe5+ dopant has influence on the intradimer interaction J0, the interdimer interaction J', and the average change rate Δχ/ΔT of spin-dimer susceptibility χdimer of Sr3Cr2−xFexO8. Especially, in this spin-dimer system, the Fe5+ dopant can obviously enhance the magnetic sensitivity of singlet to triplet transition in Sr3Cr2O8. •Sr3Cr2−xFexO8 (x=0, 0.05 and 0.1) single crystals have been grown successfully.•Magnetization sharply change confirms Sr3Cr2−xFexO8 as a spin-1/2 antiferromagnet.•Fe5+ has influence on J0, J', Δχ/ΔT of spin-dimer susceptibility χdimer.•Fe5+ dopant enhances magnetic sensitivity of Sr3Cr2O8 from singlet to triplet.</abstract><cop>Amsterdam</cop><pub>Elsevier B.V</pub><doi>10.1016/j.jmmm.2013.05.049</doi><tpages>4</tpages></addata></record>
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subjects Condensed matter: electronic structure, electrical, magnetic, and optical properties
Curie-Weiss law
Domain effects, magnetization curves, and hysteresis
Dopants
Exact sciences and technology
Iron
Magnetic fields
Magnetic materials
Magnetic permeability
Magnetic properties and materials
Magnetically ordered materials: other intrinsic properties
Magnetism
Magnetization
Magnetization curves, magnetization reversal, hysteresis, barkhausen and related effects
Physics
Saturation moments and magnetic susceptibilities
Single crystals
Spin-dimer
Transition
title Enhancement of the magnetic sensitivity of singlet to triplet transition in Fe-dopant Sr3(CrFe)2O8
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