Surface saturation control on the formation of wurtzite polytypes in zinc blende SiC nanofilms grown on Si-(100) substrates

We investigate the formations of wurtzite (WZ) SiC nano polytypes in zinc blende (ZB) SiC nanofilms hetero-grown on Si-(100) substrates via low pressure chemical vapor deposition (LPCVD) by adjusting the Si/C ratio of the introduced precursors. Through SEM, TEM, and Raman characterizations, we find...

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Veröffentlicht in:Chinese physics B 2013-08, Vol.22 (8), p.86802-1-086802-5
Hauptverfasser: Liu, Xing-Fang, Sun, Guo-Sheng, Liu, Bin, Yan, Guo-Guo, Guan, Min, Zhang, Yang, Zhang, Feng, Dong, Lin, Zheng, Liu, Liu, Sheng-Bei, Tian, Li-Xin, Wang, Lei, Zhao, Wan-Shun, Zeng, Yi-Ping
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container_end_page 1-086802-5
container_issue 8
container_start_page 86802
container_title Chinese physics B
container_volume 22
creator Liu, Xing-Fang
Sun, Guo-Sheng
Liu, Bin
Yan, Guo-Guo
Guan, Min
Zhang, Yang
Zhang, Feng
Dong, Lin
Zheng, Liu
Liu, Sheng-Bei
Tian, Li-Xin
Wang, Lei
Zhao, Wan-Shun
Zeng, Yi-Ping
description We investigate the formations of wurtzite (WZ) SiC nano polytypes in zinc blende (ZB) SiC nanofilms hetero-grown on Si-(100) substrates via low pressure chemical vapor deposition (LPCVD) by adjusting the Si/C ratio of the introduced precursors. Through SEM, TEM, and Raman characterizations, we find that the nanofilms consist of discrete WZ SiC nano polytypes and ZB SiC polytypes composed of WZ polytypes (WZ + ZB) and disordered ZB SiC polytypes, respectively, according to Si/C ratios of 0.5, 1.5, and 3. We attribute the WZ polytype formation to being due to a kinetic mechanism based on the Si/C surface saturation control.
doi_str_mv 10.1088/1674-1056/22/8/086802
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Through SEM, TEM, and Raman characterizations, we find that the nanofilms consist of discrete WZ SiC nano polytypes and ZB SiC polytypes composed of WZ polytypes (WZ + ZB) and disordered ZB SiC polytypes, respectively, according to Si/C ratios of 0.5, 1.5, and 3. We attribute the WZ polytype formation to being due to a kinetic mechanism based on the Si/C surface saturation control.</abstract><doi>10.1088/1674-1056/22/8/086802</doi></addata></record>
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subjects Blends
Formations
Nanostructure
Polytypes
Saturation
Silicon
Silicon carbide
Silicon substrates
Zinc
title Surface saturation control on the formation of wurtzite polytypes in zinc blende SiC nanofilms grown on Si-(100) substrates
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