Zinc-Catalyzed Alkene Cyclopropanation through Zinc Vinyl Carbenoids Generated from Cyclopropenes

The zinc‐catalyzed reaction of cyclopropenes with alkenes leading to vinylcyclopropane derivatives is reported. A broad range of alkenes (including highly substituted or functionalized alkenes) is compatible with this protocol. On the basis of trapping experiments and computational studies, this cyc...

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Veröffentlicht in:	Angewandte Chemie International Edition 2015-10, Vol.54 (41), p.12139-12143
Hauptverfasser:	González, María J., González, Javier, López, Luís A., Vicente, Rubén
Format:	Artikel
Sprache:	eng
Schlagworte:	Alkenes carbenes Catalysis Catalysts density functional calculations Derivatives Olefins Organic compounds small-ring compounds Strategy Zinc
Online-Zugang:	Volltext
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