High performance p-type segmented leg of misfit-layered cobaltite and half-Heusler alloy
•p-type segmented leg of oxide and half-Heusler was for the first time demonstrated.•The maximum conversion efficiency reached a value of about 5%.•The results are among the highest reported values so far for oxide-based legs.•Oxide-based segmented leg is very promising for generating electricity. I...
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Veröffentlicht in: | Energy conversion and management 2015-07, Vol.99, p.20-27 |
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creator | Hung, Le Thanh Van Nong, Ngo Snyder, G. Jeffrey Viet, Man Hoang Balke, Benjamin Han, Li Stamate, Eugen Linderoth, Søren Pryds, Nini |
description | •p-type segmented leg of oxide and half-Heusler was for the first time demonstrated.•The maximum conversion efficiency reached a value of about 5%.•The results are among the highest reported values so far for oxide-based legs.•Oxide-based segmented leg is very promising for generating electricity.
In this study, a segmented p-type leg of doped misfit-layered cobaltite Ca2.8Lu0.15Ag0.05Co4O9+δ and half-Heusler Ti0.3Zr0.35Hf0.35CoSb0.8Sn0.2 alloy was fabricated and characterized. The thermoelectric properties of single components, segmented leg, and the electrical contact resistance of the joint part were measured as a function of temperature. The output power generation characteristics of segmented legs were characterized in air under various temperature gradients, ΔT, with the hot side temperature up to 1153K. At ΔT≈756K, the maximum conversion efficiency reached a value of ∼5%, which is about 65% of that expected from the materials without parasitic losses. The long-term stability investigation for two weeks at the hot and cold side temperatures of 1153/397K shows that the segmented leg has good durability as a result of stable and low electrical resistance contacts. |
doi_str_mv | 10.1016/j.enconman.2015.03.112 |
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In this study, a segmented p-type leg of doped misfit-layered cobaltite Ca2.8Lu0.15Ag0.05Co4O9+δ and half-Heusler Ti0.3Zr0.35Hf0.35CoSb0.8Sn0.2 alloy was fabricated and characterized. The thermoelectric properties of single components, segmented leg, and the electrical contact resistance of the joint part were measured as a function of temperature. The output power generation characteristics of segmented legs were characterized in air under various temperature gradients, ΔT, with the hot side temperature up to 1153K. At ΔT≈756K, the maximum conversion efficiency reached a value of ∼5%, which is about 65% of that expected from the materials without parasitic losses. The long-term stability investigation for two weeks at the hot and cold side temperatures of 1153/397K shows that the segmented leg has good durability as a result of stable and low electrical resistance contacts.</description><identifier>ISSN: 0196-8904</identifier><identifier>EISSN: 1879-2227</identifier><identifier>DOI: 10.1016/j.enconman.2015.03.112</identifier><language>eng</language><publisher>Elsevier Ltd</publisher><subject>Approximation ; Contact ; Contact resistance ; Conversion ; Electric contacts ; Electrical resistance ; Legs ; Power generation efficiency ; Segmented oxide-metal alloy ; Segmented thermoelectrics ; Thermoelectric efficiency ; Thermoelectricity</subject><ispartof>Energy conversion and management, 2015-07, Vol.99, p.20-27</ispartof><rights>2015 Elsevier Ltd</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c386t-e592ebbb163f0d6f4b37db30ce1b8405250b436270f6ab48f88fcddcd42b0eaa3</citedby><cites>FETCH-LOGICAL-c386t-e592ebbb163f0d6f4b37db30ce1b8405250b436270f6ab48f88fcddcd42b0eaa3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktohtml>$$Uhttps://www.sciencedirect.com/science/article/pii/S0196890415003386$$EHTML$$P50$$Gelsevier$$H</linktohtml><link.rule.ids>314,776,780,3537,27901,27902,65306</link.rule.ids></links><search><creatorcontrib>Hung, Le Thanh</creatorcontrib><creatorcontrib>Van Nong, Ngo</creatorcontrib><creatorcontrib>Snyder, G. Jeffrey</creatorcontrib><creatorcontrib>Viet, Man Hoang</creatorcontrib><creatorcontrib>Balke, Benjamin</creatorcontrib><creatorcontrib>Han, Li</creatorcontrib><creatorcontrib>Stamate, Eugen</creatorcontrib><creatorcontrib>Linderoth, Søren</creatorcontrib><creatorcontrib>Pryds, Nini</creatorcontrib><title>High performance p-type segmented leg of misfit-layered cobaltite and half-Heusler alloy</title><title>Energy conversion and management</title><description>•p-type segmented leg of oxide and half-Heusler was for the first time demonstrated.•The maximum conversion efficiency reached a value of about 5%.•The results are among the highest reported values so far for oxide-based legs.•Oxide-based segmented leg is very promising for generating electricity.
In this study, a segmented p-type leg of doped misfit-layered cobaltite Ca2.8Lu0.15Ag0.05Co4O9+δ and half-Heusler Ti0.3Zr0.35Hf0.35CoSb0.8Sn0.2 alloy was fabricated and characterized. The thermoelectric properties of single components, segmented leg, and the electrical contact resistance of the joint part were measured as a function of temperature. The output power generation characteristics of segmented legs were characterized in air under various temperature gradients, ΔT, with the hot side temperature up to 1153K. At ΔT≈756K, the maximum conversion efficiency reached a value of ∼5%, which is about 65% of that expected from the materials without parasitic losses. The long-term stability investigation for two weeks at the hot and cold side temperatures of 1153/397K shows that the segmented leg has good durability as a result of stable and low electrical resistance contacts.</description><subject>Approximation</subject><subject>Contact</subject><subject>Contact resistance</subject><subject>Conversion</subject><subject>Electric contacts</subject><subject>Electrical resistance</subject><subject>Legs</subject><subject>Power generation efficiency</subject><subject>Segmented oxide-metal alloy</subject><subject>Segmented thermoelectrics</subject><subject>Thermoelectric efficiency</subject><subject>Thermoelectricity</subject><issn>0196-8904</issn><issn>1879-2227</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2015</creationdate><recordtype>article</recordtype><recordid>eNqFkE1r3DAQhkVIIJtN_kLQMRe7I8mW7VtKaLOBQC4p9Cb0Mdpo0Vqu5C3sv6-XTc85DQzP-zLzEHLPoGbA5LddjaNN416PNQfW1iBqxvgFWbG-GyrOeXdJVsAGWfUDNNfkppQdAIgW5Ir83oTtB50w-5SXBot0qubjhLTgdo_jjI5G3NLk6T4UH-Yq6iPmZWuT0XEOM1I9Ovqho682eCgRM9UxpuMtufI6Frz7nGvy6-eP96dN9fr2_PL0_bWyopdzhe3A0RjDpPDgpG-M6JwRYJGZvoGWt2AaIXkHXmrT9L7vvXXOuoYbQK3Fmjyce6ec_hywzGo51GKMesR0KIp1rWgb1stuQeUZtTmVktGrKYe9zkfFQJ1Uqp36r1KdVCoQalG5BB_PQVwe-Rswq2LDQqILGe2sXApfVfwDJlSB0A</recordid><startdate>20150715</startdate><enddate>20150715</enddate><creator>Hung, Le Thanh</creator><creator>Van Nong, Ngo</creator><creator>Snyder, G. Jeffrey</creator><creator>Viet, Man Hoang</creator><creator>Balke, Benjamin</creator><creator>Han, Li</creator><creator>Stamate, Eugen</creator><creator>Linderoth, Søren</creator><creator>Pryds, Nini</creator><general>Elsevier Ltd</general><scope>AAYXX</scope><scope>CITATION</scope><scope>7TB</scope><scope>8BQ</scope><scope>8FD</scope><scope>FR3</scope><scope>H8D</scope><scope>JG9</scope><scope>KR7</scope><scope>L7M</scope></search><sort><creationdate>20150715</creationdate><title>High performance p-type segmented leg of misfit-layered cobaltite and half-Heusler alloy</title><author>Hung, Le Thanh ; Van Nong, Ngo ; Snyder, G. Jeffrey ; Viet, Man Hoang ; Balke, Benjamin ; Han, Li ; Stamate, Eugen ; Linderoth, Søren ; Pryds, Nini</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c386t-e592ebbb163f0d6f4b37db30ce1b8405250b436270f6ab48f88fcddcd42b0eaa3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2015</creationdate><topic>Approximation</topic><topic>Contact</topic><topic>Contact resistance</topic><topic>Conversion</topic><topic>Electric contacts</topic><topic>Electrical resistance</topic><topic>Legs</topic><topic>Power generation efficiency</topic><topic>Segmented oxide-metal alloy</topic><topic>Segmented thermoelectrics</topic><topic>Thermoelectric efficiency</topic><topic>Thermoelectricity</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Hung, Le Thanh</creatorcontrib><creatorcontrib>Van Nong, Ngo</creatorcontrib><creatorcontrib>Snyder, G. Jeffrey</creatorcontrib><creatorcontrib>Viet, Man Hoang</creatorcontrib><creatorcontrib>Balke, Benjamin</creatorcontrib><creatorcontrib>Han, Li</creatorcontrib><creatorcontrib>Stamate, Eugen</creatorcontrib><creatorcontrib>Linderoth, Søren</creatorcontrib><creatorcontrib>Pryds, Nini</creatorcontrib><collection>CrossRef</collection><collection>Mechanical & Transportation Engineering Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Engineering Research Database</collection><collection>Aerospace Database</collection><collection>Materials Research Database</collection><collection>Civil Engineering Abstracts</collection><collection>Advanced Technologies Database with Aerospace</collection><jtitle>Energy conversion and management</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Hung, Le Thanh</au><au>Van Nong, Ngo</au><au>Snyder, G. Jeffrey</au><au>Viet, Man Hoang</au><au>Balke, Benjamin</au><au>Han, Li</au><au>Stamate, Eugen</au><au>Linderoth, Søren</au><au>Pryds, Nini</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>High performance p-type segmented leg of misfit-layered cobaltite and half-Heusler alloy</atitle><jtitle>Energy conversion and management</jtitle><date>2015-07-15</date><risdate>2015</risdate><volume>99</volume><spage>20</spage><epage>27</epage><pages>20-27</pages><issn>0196-8904</issn><eissn>1879-2227</eissn><abstract>•p-type segmented leg of oxide and half-Heusler was for the first time demonstrated.•The maximum conversion efficiency reached a value of about 5%.•The results are among the highest reported values so far for oxide-based legs.•Oxide-based segmented leg is very promising for generating electricity.
In this study, a segmented p-type leg of doped misfit-layered cobaltite Ca2.8Lu0.15Ag0.05Co4O9+δ and half-Heusler Ti0.3Zr0.35Hf0.35CoSb0.8Sn0.2 alloy was fabricated and characterized. The thermoelectric properties of single components, segmented leg, and the electrical contact resistance of the joint part were measured as a function of temperature. The output power generation characteristics of segmented legs were characterized in air under various temperature gradients, ΔT, with the hot side temperature up to 1153K. At ΔT≈756K, the maximum conversion efficiency reached a value of ∼5%, which is about 65% of that expected from the materials without parasitic losses. The long-term stability investigation for two weeks at the hot and cold side temperatures of 1153/397K shows that the segmented leg has good durability as a result of stable and low electrical resistance contacts.</abstract><pub>Elsevier Ltd</pub><doi>10.1016/j.enconman.2015.03.112</doi><tpages>8</tpages></addata></record> |
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subjects | Approximation Contact Contact resistance Conversion Electric contacts Electrical resistance Legs Power generation efficiency Segmented oxide-metal alloy Segmented thermoelectrics Thermoelectric efficiency Thermoelectricity |
title | High performance p-type segmented leg of misfit-layered cobaltite and half-Heusler alloy |
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