Decomposition of Lignin from Sugar Cane Bagasse during Ozonation Process Monitored by Optical and Mass Spectrometries
Mass spectrometry was used to monitor neutral chemical species from sugar cane bagasse that could volatilize during the bagasse ozonation process. Lignin fragments and some radicals liberated by direct ozone reaction with the biomass structure were detected. Ozone density was monitored during the oz...
Gespeichert in:
| Veröffentlicht in: | The journal of physical chemistry. B 2013-03, Vol.117 (11), p.3110-3119 |
|---|---|
| Hauptverfasser: | , , , , |
| Format: | Artikel |
| Sprache: | eng |
| Schlagworte: | |
| Online-Zugang: | Volltext |
| Tags: |
Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
|
| container_end_page | 3119 |
|---|---|
| container_issue | 11 |
| container_start_page | 3110 |
| container_title | The journal of physical chemistry. B |
| container_volume | 117 |
| creator | Souza-Corrêa, J. A Ridenti, M. A Oliveira, C Araújo, S. R Amorim, J |
| description | Mass spectrometry was used to monitor neutral chemical species from sugar cane bagasse that could volatilize during the bagasse ozonation process. Lignin fragments and some radicals liberated by direct ozone reaction with the biomass structure were detected. Ozone density was monitored during the ozonation by optical absorption spectroscopy. The optical results indicated that the ozone interaction with the bagasse material was better for bagasse particle sizes less than or equal to 0.5 mm. Both techniques have shown that the best condition for the ozone diffusion in the bagasse was at 50% of its moisture content. In addition, Fourier transform infrared spectroscopy (FTIR) and scanning electron microscopy (SEM) were employed to analyze the lignin bond disruptions and morphology changes of the bagasse surface that occurred due to the ozonolysis reactions as well. Appropriate chemical characterization of the lignin content in bagasse before and after its ozonation was also carried out. |
| doi_str_mv | 10.1021/jp3121879 |
| format | Article |
| fullrecord | <record><control><sourceid>proquest_cross</sourceid><recordid>TN_cdi_proquest_miscellaneous_1753510486</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>1753510486</sourcerecordid><originalsourceid>FETCH-LOGICAL-a444t-fa52da3db695f76645664c68f94f3d2ac3daeae472272394d0f6d413060628d23</originalsourceid><addsrcrecordid>eNqF0TtvFDEQB3ALEZEQKPIFkBukUBzxa-3dklx4SRddpEC9mvPj5NOtvXh2i_DpcciRUCBRjOziN2N5_oSccfaeM8EvdqPkgreme0ZOeCPYopZ5frhrzvQxeYm4Y0w0otUvyLGQSlXfnJD5yts8jBnjFHOiOdBV3KaYaCh5oLfzFgpdQvL0EraA6KmbS0xbuv6ZE_xuuSnZekR6nVOccvGObu7oepyihT2F5Oh17aO3o7dTHemnEj2-IkcB9uhfH85T8v3Tx2_LL4vV-vPX5YfVApRS0yJAIxxIt9FdE4zWqqlldRs6FaQTYKUDD14ZIYyQnXIsaKe4ZJpp0TohT8n5w9yx5B-zx6kfIlq_39cf5Rl7bhrZcKZa_X8qeccNM5pX-u6B2pIRiw_9WOIA5a7nrL8PpH8MpNo3h7HzZvDuUf5JoIK3BwBYNxYKJBvxyRnBudZ_ObDY7_JcUl3cPx78BfdLnhI</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>1319170761</pqid></control><display><type>article</type><title>Decomposition of Lignin from Sugar Cane Bagasse during Ozonation Process Monitored by Optical and Mass Spectrometries</title><source>MEDLINE</source><source>American Chemical Society Journals</source><creator>Souza-Corrêa, J. A ; Ridenti, M. A ; Oliveira, C ; Araújo, S. R ; Amorim, J</creator><creatorcontrib>Souza-Corrêa, J. A ; Ridenti, M. A ; Oliveira, C ; Araújo, S. R ; Amorim, J</creatorcontrib><description>Mass spectrometry was used to monitor neutral chemical species from sugar cane bagasse that could volatilize during the bagasse ozonation process. Lignin fragments and some radicals liberated by direct ozone reaction with the biomass structure were detected. Ozone density was monitored during the ozonation by optical absorption spectroscopy. The optical results indicated that the ozone interaction with the bagasse material was better for bagasse particle sizes less than or equal to 0.5 mm. Both techniques have shown that the best condition for the ozone diffusion in the bagasse was at 50% of its moisture content. In addition, Fourier transform infrared spectroscopy (FTIR) and scanning electron microscopy (SEM) were employed to analyze the lignin bond disruptions and morphology changes of the bagasse surface that occurred due to the ozonolysis reactions as well. Appropriate chemical characterization of the lignin content in bagasse before and after its ozonation was also carried out.</description><identifier>ISSN: 1520-6106</identifier><identifier>EISSN: 1520-5207</identifier><identifier>DOI: 10.1021/jp3121879</identifier><identifier>PMID: 23441875</identifier><language>eng</language><publisher>Washington, DC: American Chemical Society</publisher><subject>Bagasse ; Biological and medical sciences ; Biomass ; Cellulose - chemistry ; Density ; Food industries ; Fourier transforms ; Fundamental and applied biological sciences. Psychology ; Infrared spectroscopy ; Lignin - chemistry ; Mass Spectrometry ; Ozone ; Ozone - chemistry ; Saccharum - metabolism ; Scanning electron microscopy ; Spectroscopy, Fourier Transform Infrared ; Sugar cane ; Sugar industries</subject><ispartof>The journal of physical chemistry. B, 2013-03, Vol.117 (11), p.3110-3119</ispartof><rights>Copyright © 2013 American Chemical Society</rights><rights>2014 INIST-CNRS</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-a444t-fa52da3db695f76645664c68f94f3d2ac3daeae472272394d0f6d413060628d23</citedby><cites>FETCH-LOGICAL-a444t-fa52da3db695f76645664c68f94f3d2ac3daeae472272394d0f6d413060628d23</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://pubs.acs.org/doi/pdf/10.1021/jp3121879$$EPDF$$P50$$Gacs$$H</linktopdf><linktohtml>$$Uhttps://pubs.acs.org/doi/10.1021/jp3121879$$EHTML$$P50$$Gacs$$H</linktohtml><link.rule.ids>314,776,780,2752,27053,27901,27902,56713,56763</link.rule.ids><backlink>$$Uhttp://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&idt=27211665$$DView record in Pascal Francis$$Hfree_for_read</backlink><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/23441875$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>Souza-Corrêa, J. A</creatorcontrib><creatorcontrib>Ridenti, M. A</creatorcontrib><creatorcontrib>Oliveira, C</creatorcontrib><creatorcontrib>Araújo, S. R</creatorcontrib><creatorcontrib>Amorim, J</creatorcontrib><title>Decomposition of Lignin from Sugar Cane Bagasse during Ozonation Process Monitored by Optical and Mass Spectrometries</title><title>The journal of physical chemistry. B</title><addtitle>J. Phys. Chem. B</addtitle><description>Mass spectrometry was used to monitor neutral chemical species from sugar cane bagasse that could volatilize during the bagasse ozonation process. Lignin fragments and some radicals liberated by direct ozone reaction with the biomass structure were detected. Ozone density was monitored during the ozonation by optical absorption spectroscopy. The optical results indicated that the ozone interaction with the bagasse material was better for bagasse particle sizes less than or equal to 0.5 mm. Both techniques have shown that the best condition for the ozone diffusion in the bagasse was at 50% of its moisture content. In addition, Fourier transform infrared spectroscopy (FTIR) and scanning electron microscopy (SEM) were employed to analyze the lignin bond disruptions and morphology changes of the bagasse surface that occurred due to the ozonolysis reactions as well. Appropriate chemical characterization of the lignin content in bagasse before and after its ozonation was also carried out.</description><subject>Bagasse</subject><subject>Biological and medical sciences</subject><subject>Biomass</subject><subject>Cellulose - chemistry</subject><subject>Density</subject><subject>Food industries</subject><subject>Fourier transforms</subject><subject>Fundamental and applied biological sciences. Psychology</subject><subject>Infrared spectroscopy</subject><subject>Lignin - chemistry</subject><subject>Mass Spectrometry</subject><subject>Ozone</subject><subject>Ozone - chemistry</subject><subject>Saccharum - metabolism</subject><subject>Scanning electron microscopy</subject><subject>Spectroscopy, Fourier Transform Infrared</subject><subject>Sugar cane</subject><subject>Sugar industries</subject><issn>1520-6106</issn><issn>1520-5207</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2013</creationdate><recordtype>article</recordtype><sourceid>EIF</sourceid><recordid>eNqF0TtvFDEQB3ALEZEQKPIFkBukUBzxa-3dklx4SRddpEC9mvPj5NOtvXh2i_DpcciRUCBRjOziN2N5_oSccfaeM8EvdqPkgreme0ZOeCPYopZ5frhrzvQxeYm4Y0w0otUvyLGQSlXfnJD5yts8jBnjFHOiOdBV3KaYaCh5oLfzFgpdQvL0EraA6KmbS0xbuv6ZE_xuuSnZekR6nVOccvGObu7oepyihT2F5Oh17aO3o7dTHemnEj2-IkcB9uhfH85T8v3Tx2_LL4vV-vPX5YfVApRS0yJAIxxIt9FdE4zWqqlldRs6FaQTYKUDD14ZIYyQnXIsaKe4ZJpp0TohT8n5w9yx5B-zx6kfIlq_39cf5Rl7bhrZcKZa_X8qeccNM5pX-u6B2pIRiw_9WOIA5a7nrL8PpH8MpNo3h7HzZvDuUf5JoIK3BwBYNxYKJBvxyRnBudZ_ObDY7_JcUl3cPx78BfdLnhI</recordid><startdate>20130321</startdate><enddate>20130321</enddate><creator>Souza-Corrêa, J. A</creator><creator>Ridenti, M. A</creator><creator>Oliveira, C</creator><creator>Araújo, S. R</creator><creator>Amorim, J</creator><general>American Chemical Society</general><scope>IQODW</scope><scope>CGR</scope><scope>CUY</scope><scope>CVF</scope><scope>ECM</scope><scope>EIF</scope><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7X8</scope><scope>7SR</scope><scope>7U5</scope><scope>8BQ</scope><scope>8FD</scope><scope>JG9</scope><scope>L7M</scope></search><sort><creationdate>20130321</creationdate><title>Decomposition of Lignin from Sugar Cane Bagasse during Ozonation Process Monitored by Optical and Mass Spectrometries</title><author>Souza-Corrêa, J. A ; Ridenti, M. A ; Oliveira, C ; Araújo, S. R ; Amorim, J</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-a444t-fa52da3db695f76645664c68f94f3d2ac3daeae472272394d0f6d413060628d23</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2013</creationdate><topic>Bagasse</topic><topic>Biological and medical sciences</topic><topic>Biomass</topic><topic>Cellulose - chemistry</topic><topic>Density</topic><topic>Food industries</topic><topic>Fourier transforms</topic><topic>Fundamental and applied biological sciences. Psychology</topic><topic>Infrared spectroscopy</topic><topic>Lignin - chemistry</topic><topic>Mass Spectrometry</topic><topic>Ozone</topic><topic>Ozone - chemistry</topic><topic>Saccharum - metabolism</topic><topic>Scanning electron microscopy</topic><topic>Spectroscopy, Fourier Transform Infrared</topic><topic>Sugar cane</topic><topic>Sugar industries</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Souza-Corrêa, J. A</creatorcontrib><creatorcontrib>Ridenti, M. A</creatorcontrib><creatorcontrib>Oliveira, C</creatorcontrib><creatorcontrib>Araújo, S. R</creatorcontrib><creatorcontrib>Amorim, J</creatorcontrib><collection>Pascal-Francis</collection><collection>Medline</collection><collection>MEDLINE</collection><collection>MEDLINE (Ovid)</collection><collection>MEDLINE</collection><collection>MEDLINE</collection><collection>PubMed</collection><collection>CrossRef</collection><collection>MEDLINE - Academic</collection><collection>Engineered Materials Abstracts</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><collection>Advanced Technologies Database with Aerospace</collection><jtitle>The journal of physical chemistry. B</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Souza-Corrêa, J. A</au><au>Ridenti, M. A</au><au>Oliveira, C</au><au>Araújo, S. R</au><au>Amorim, J</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Decomposition of Lignin from Sugar Cane Bagasse during Ozonation Process Monitored by Optical and Mass Spectrometries</atitle><jtitle>The journal of physical chemistry. B</jtitle><addtitle>J. Phys. Chem. B</addtitle><date>2013-03-21</date><risdate>2013</risdate><volume>117</volume><issue>11</issue><spage>3110</spage><epage>3119</epage><pages>3110-3119</pages><issn>1520-6106</issn><eissn>1520-5207</eissn><abstract>Mass spectrometry was used to monitor neutral chemical species from sugar cane bagasse that could volatilize during the bagasse ozonation process. Lignin fragments and some radicals liberated by direct ozone reaction with the biomass structure were detected. Ozone density was monitored during the ozonation by optical absorption spectroscopy. The optical results indicated that the ozone interaction with the bagasse material was better for bagasse particle sizes less than or equal to 0.5 mm. Both techniques have shown that the best condition for the ozone diffusion in the bagasse was at 50% of its moisture content. In addition, Fourier transform infrared spectroscopy (FTIR) and scanning electron microscopy (SEM) were employed to analyze the lignin bond disruptions and morphology changes of the bagasse surface that occurred due to the ozonolysis reactions as well. Appropriate chemical characterization of the lignin content in bagasse before and after its ozonation was also carried out.</abstract><cop>Washington, DC</cop><pub>American Chemical Society</pub><pmid>23441875</pmid><doi>10.1021/jp3121879</doi><tpages>10</tpages></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 1520-6106 |
| ispartof | The journal of physical chemistry. B, 2013-03, Vol.117 (11), p.3110-3119 |
| issn | 1520-6106 1520-5207 |
| language | eng |
| recordid | cdi_proquest_miscellaneous_1753510486 |
| source | MEDLINE; American Chemical Society Journals |
| subjects | Bagasse Biological and medical sciences Biomass Cellulose - chemistry Density Food industries Fourier transforms Fundamental and applied biological sciences. Psychology Infrared spectroscopy Lignin - chemistry Mass Spectrometry Ozone Ozone - chemistry Saccharum - metabolism Scanning electron microscopy Spectroscopy, Fourier Transform Infrared Sugar cane Sugar industries |
| title | Decomposition of Lignin from Sugar Cane Bagasse during Ozonation Process Monitored by Optical and Mass Spectrometries |
| url | https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2025-02-18T21%3A49%3A47IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-proquest_cross&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Decomposition%20of%20Lignin%20from%20Sugar%20Cane%20Bagasse%20during%20Ozonation%20Process%20Monitored%20by%20Optical%20and%20Mass%20Spectrometries&rft.jtitle=The%20journal%20of%20physical%20chemistry.%20B&rft.au=Souza-Corre%CC%82a,%20J.%20A&rft.date=2013-03-21&rft.volume=117&rft.issue=11&rft.spage=3110&rft.epage=3119&rft.pages=3110-3119&rft.issn=1520-6106&rft.eissn=1520-5207&rft_id=info:doi/10.1021/jp3121879&rft_dat=%3Cproquest_cross%3E1753510486%3C/proquest_cross%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_pqid=1319170761&rft_id=info:pmid/23441875&rfr_iscdi=true |