Structure of Iron Ions in Some Acetone Based Electrolytes
X-ray absorption, Mössbauer, and Raman spectroscopy were combined to determine the local environment of iron ions in acetone based solutions of FeCl2. It is shown that part of the Fe(II) ions change their oxidation state, accompanied by symmetry change from octahedral Fe(H2O)6 2+ to tetrahedral [Fe...
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| Veröffentlicht in: | The journal of physical chemistry. A, Molecules, spectroscopy, kinetics, environment, & general theory Molecules, spectroscopy, kinetics, environment, & general theory, 2013-03, Vol.117 (10), p.2190-2194 |
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| container_title | The journal of physical chemistry. A, Molecules, spectroscopy, kinetics, environment, & general theory |
| container_volume | 117 |
| creator | Olszewski, Wojciech Szymański, Krzysztof Satuła, Dariusz Kalska-Szostko, Beata |
| description | X-ray absorption, Mössbauer, and Raman spectroscopy were combined to determine the local environment of iron ions in acetone based solutions of FeCl2. It is shown that part of the Fe(II) ions change their oxidation state, accompanied by symmetry change from octahedral Fe(H2O)6 2+ to tetrahedral [FeCl4]− at large acetone concentrations. The ratio of Fe(II)/Fe(III) determined by Mössbauer spectroscopy agrees well with that determined by the X-ray absorption studies. Raman measurements confirm quantitative estimations of [FeCl4]− species in acetone rich solutions. |
| doi_str_mv | 10.1021/jp400556d |
| format | Article |
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It is shown that part of the Fe(II) ions change their oxidation state, accompanied by symmetry change from octahedral Fe(H2O)6 2+ to tetrahedral [FeCl4]− at large acetone concentrations. The ratio of Fe(II)/Fe(III) determined by Mössbauer spectroscopy agrees well with that determined by the X-ray absorption studies. Raman measurements confirm quantitative estimations of [FeCl4]− species in acetone rich solutions.</description><identifier>ISSN: 1089-5639</identifier><identifier>EISSN: 1520-5215</identifier><identifier>DOI: 10.1021/jp400556d</identifier><identifier>PMID: 23425339</identifier><language>eng</language><publisher>Washington, DC: American Chemical Society</publisher><subject>Acetone ; Chemistry ; Condensed matter: structure, mechanical and thermal properties ; Electrochemistry ; Electrolytes ; Exact sciences and technology ; General and physical chemistry ; Iron ; Mossbauer effect ; Mossbauer spectroscopy ; Physical chemistry ; Physics ; Properties of electrolytes: conductivity ; Structure of associated liquids: electrolytes, molten salts, etc ; Structure of liquids ; Structure of solids and liquids; crystallography ; Symmetry ; X-rays</subject><ispartof>The journal of physical chemistry. 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A, Molecules, spectroscopy, kinetics, environment, & general theory</title><addtitle>J. Phys. Chem. A</addtitle><description>X-ray absorption, Mössbauer, and Raman spectroscopy were combined to determine the local environment of iron ions in acetone based solutions of FeCl2. It is shown that part of the Fe(II) ions change their oxidation state, accompanied by symmetry change from octahedral Fe(H2O)6 2+ to tetrahedral [FeCl4]− at large acetone concentrations. The ratio of Fe(II)/Fe(III) determined by Mössbauer spectroscopy agrees well with that determined by the X-ray absorption studies. Raman measurements confirm quantitative estimations of [FeCl4]− species in acetone rich solutions.</description><subject>Acetone</subject><subject>Chemistry</subject><subject>Condensed matter: structure, mechanical and thermal properties</subject><subject>Electrochemistry</subject><subject>Electrolytes</subject><subject>Exact sciences and technology</subject><subject>General and physical chemistry</subject><subject>Iron</subject><subject>Mossbauer effect</subject><subject>Mossbauer spectroscopy</subject><subject>Physical chemistry</subject><subject>Physics</subject><subject>Properties of electrolytes: conductivity</subject><subject>Structure of associated liquids: electrolytes, molten salts, etc</subject><subject>Structure of liquids</subject><subject>Structure of solids and liquids; crystallography</subject><subject>Symmetry</subject><subject>X-rays</subject><issn>1089-5639</issn><issn>1520-5215</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2013</creationdate><recordtype>article</recordtype><recordid>eNqF0D1PwzAQBmALgSgUBv4A8oIEQ8Dnz3gsVYFKlRgKc-Q4tpQqjYudDP33BLW0CxLT3fDovdOL0A2QRyAUnlYbTogQsjpBFyAoyQQFcTrsJNeZkEyP0GVKK0IIMMrP0YgyTgVj-gLpZRd72_XR4eDxPIYWz0ObcN3iZVg7PLGuC63Dzya5Cs8aZ7sYmm3n0hU686ZJ7no_x-jzZfYxfcsW76_z6WSRGabyLqtyalhJS0m8sHluPAdTOa0EZdpzLn2unK2Gr6XMLeceeM4ZCMVKUdrKlGyM7ne5mxi-epe6Yl0n65rGtC70qQAlmCCcgv6fMlCcSKphoA87amNIKTpfbGK9NnFbACl-Si0OpQ72dh_bl2tXHeRviwO42wOTrGl8NK2t09EpCiC1OjpjU7EKfWyH4v44-A0qmYgh</recordid><startdate>20130314</startdate><enddate>20130314</enddate><creator>Olszewski, Wojciech</creator><creator>Szymański, Krzysztof</creator><creator>Satuła, Dariusz</creator><creator>Kalska-Szostko, Beata</creator><general>American Chemical Society</general><scope>IQODW</scope><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7X8</scope><scope>7SR</scope><scope>7U5</scope><scope>8BQ</scope><scope>8FD</scope><scope>JG9</scope><scope>L7M</scope></search><sort><creationdate>20130314</creationdate><title>Structure of Iron Ions in Some Acetone Based Electrolytes</title><author>Olszewski, Wojciech ; Szymański, Krzysztof ; Satuła, Dariusz ; Kalska-Szostko, Beata</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-a378t-d82a3b2b60f5c88af41ade975239f446f87ecd152668c44f148431573b5bcdab3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2013</creationdate><topic>Acetone</topic><topic>Chemistry</topic><topic>Condensed matter: structure, mechanical and thermal properties</topic><topic>Electrochemistry</topic><topic>Electrolytes</topic><topic>Exact sciences and technology</topic><topic>General and physical chemistry</topic><topic>Iron</topic><topic>Mossbauer effect</topic><topic>Mossbauer spectroscopy</topic><topic>Physical chemistry</topic><topic>Physics</topic><topic>Properties of electrolytes: conductivity</topic><topic>Structure of associated liquids: electrolytes, molten salts, etc</topic><topic>Structure of liquids</topic><topic>Structure of solids and liquids; crystallography</topic><topic>Symmetry</topic><topic>X-rays</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Olszewski, Wojciech</creatorcontrib><creatorcontrib>Szymański, Krzysztof</creatorcontrib><creatorcontrib>Satuła, Dariusz</creatorcontrib><creatorcontrib>Kalska-Szostko, Beata</creatorcontrib><collection>Pascal-Francis</collection><collection>PubMed</collection><collection>CrossRef</collection><collection>MEDLINE - Academic</collection><collection>Engineered Materials Abstracts</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><collection>Advanced Technologies Database with Aerospace</collection><jtitle>The journal of physical chemistry. 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| source | ACS Publications |
| subjects | Acetone Chemistry Condensed matter: structure, mechanical and thermal properties Electrochemistry Electrolytes Exact sciences and technology General and physical chemistry Iron Mossbauer effect Mossbauer spectroscopy Physical chemistry Physics Properties of electrolytes: conductivity Structure of associated liquids: electrolytes, molten salts, etc Structure of liquids Structure of solids and liquids crystallography Symmetry X-rays |
| title | Structure of Iron Ions in Some Acetone Based Electrolytes |
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