Dynamical Excimer Formation in Rigid Carbazolophane via Charge Transfer State

Formation dynamics of intramolecular excimer in dioxa[3.3](3,6)carbazolophane (CzOCz) was studied by time-resolved spectroscopic methods and computational calculations. In the ground state, the most stable conformer in CzOCz is the anti-conformation where two carbazole rings are in antiparallel alig...

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Veröffentlicht in:	The journal of physical chemistry. A, Molecules, spectroscopy, kinetics, environment, & general theory Molecules, spectroscopy, kinetics, environment, & general theory, 2013-08, Vol.117 (33), p.7776-7785
Hauptverfasser:	Tamai, Yasunari, Ohkita, Hideo, Shimada, Jiro, Benten, Hiroaki, Ito, Shinzaburo, Yamanaka, Sho, Hisada, Kenji, Tani, Keita, Kubono, Koji, Shinmyozu, Teruo
Format:	Artikel
Sprache:	eng
Schlagworte:	Atomic and molecular physics Carbazoles Charge transfer Exact sciences and technology Excimers Fluorescence and phosphorescence spectra Fluorescence and phosphorescence radiationless transitions, quenching (intersystem crossing, internal conversion) Formations Ground state Isomers Mathematical analysis Molecular properties and interactions with photons Molecular spectra Physics Solvents
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