A one-step, modular route to optically-active diphos ligands

A one-step, modular route to optically-active diphos ligands

A chlorosilane elimination reaction has been developed that allows the efficient synthesis of optically pure C1-symmetric, C1-backboned diphosphines with a wide variety of stereoelectronic characteristics.

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Veröffentlicht in:Chemical communications (Cambridge, England) England), 2015-01, Vol.51 (50), p.10206-10209
Hauptverfasser: Louise Hazeland, E, Chapman, Andy M, Pringle, Paul G, Sparkes, Hazel A
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Sprache:eng
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Chlorosilanes
Ligands
Modular
Synthesis (chemistry)
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container_issue 50
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container_title Chemical communications (Cambridge, England)
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creator Louise Hazeland, E
Chapman, Andy M
Pringle, Paul G
Sparkes, Hazel A
description A chlorosilane elimination reaction has been developed that allows the efficient synthesis of optically pure C1-symmetric, C1-backboned diphosphines with a wide variety of stereoelectronic characteristics.
doi_str_mv 10.1039/c5cc03517a
format Article
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source Royal Society Of Chemistry Journals 2008-; Alma/SFX Local Collection
subjects Chlorosilanes
Ligands
Modular
Synthesis (chemistry)
title A one-step, modular route to optically-active diphos ligands
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