A one-step, modular route to optically-active diphos ligands

A one-step, modular route to optically-active diphos ligands

A chlorosilane elimination reaction has been developed that allows the efficient synthesis of optically pure C1-symmetric, C1-backboned diphosphines with a wide variety of stereoelectronic characteristics.

Gespeichert in:
Bibliographische Detailangaben
Veröffentlicht in:Chemical communications (Cambridge, England) England), 2015-01, Vol.51 (50), p.10206-10209
Hauptverfasser: Louise Hazeland, E, Chapman, Andy M, Pringle, Paul G, Sparkes, Hazel A
Format: Artikel
Sprache:eng
Schlagworte:
Chlorosilanes
Ligands
Modular
Synthesis (chemistry)
Online-Zugang:Volltext
Tags: Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
Beschreibung
Zusammenfassung:A chlorosilane elimination reaction has been developed that allows the efficient synthesis of optically pure C1-symmetric, C1-backboned diphosphines with a wide variety of stereoelectronic characteristics.
ISSN:1359-7345
1364-548X
DOI:10.1039/c5cc03517a