High-Temperature Measurements of the Reactions of OH with a Series of Ketones: Acetone, 2-Butanone, 3-Pentanone, and 2-Pentanone

The overall rate constants for the reactions of hydroxyl radicals (OH) with a series of ketones, namely, acetone (CH3COCH3), 2-butanone (C2H5COCH3), 3-pentanone (C2H5COC2H5), and 2-pentanone (C3H7COCH3), were studied behind reflected shock waves over the temperature range of 870–1360 K at pressures...

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Veröffentlicht in:	The journal of physical chemistry. A, Molecules, spectroscopy, kinetics, environment, & general theory Molecules, spectroscopy, kinetics, environment, & general theory, 2012-06, Vol.116 (23), p.5549-5559
Hauptverfasser:	Lam, King-Yiu, Davidson, David F, Hanson, Ronald K
Format:	Artikel
Sprache:	eng
Schlagworte:	Acetone Estimates Hydroxyl radicals Ketones Mathematical models Rate constants Shock waves Thermal decomposition
Online-Zugang:	Volltext
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