A Reduced 2Fe2S Cluster Probe of Sulfur-Hydrogen versus Sulfur-Gold Interactions

The Ph3PAu+ cation, renowned as an isolobal analogue of H+, was found to serve as a proton surrogate and form a stable Au2Fe2 complex, [(μ‐SAuPPh3)2{Fe(CO)3}2], analogous to the highly reactive dihydrosulfide [(μ‐SH)2{Fe(CO)3}2]. Solid‐state X‐ray diffraction analysis found the two SAuPPh3 and SH br...

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Veröffentlicht in:	Angewandte Chemie 2015-09, Vol.127 (38), p.11254-11258
Hauptverfasser:	Crouthers, Danielle J., Ding, Shengda, Denny, Jason A., Bethel, Ryan D., Hsieh, Chung-Hung, Hall, Michael B., Darensbourg, Marcetta Y.
Format:	Artikel
Sprache:	eng ; ger
Schlagworte:	Analogue Balancing Barriers Biomimetics Bonding Chemistry Diffraction Fe-S-Au-Cluster Hydrogenasen Hydrosulfide Isolobale Spezies Ligands Precursors Schwefelinversion X-rays
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