Multi-edge X‑ray Absorption Spectroscopy. 1. X‑ray Absorption near-Edge Structure Analysis of a Biomimetic Model of FeFe-Hydrogenase

In this work, we demonstrate the potential of multi-edge X-ray absorption near-edge structure (XANES) analysis in completely defining the ground state electronic structure of a prototypical biomimetic complex of the [2Fe]-subcluster of the catalytic H-cluster of FeFe-hydrogenase. The spectral featur...

Ausführliche Beschreibung

Gespeichert in:

Bibliographische Detailangaben
Veröffentlicht in:	The journal of physical chemistry. A, Molecules, spectroscopy, kinetics, environment, & general theory Molecules, spectroscopy, kinetics, environment, & general theory, 2012-12, Vol.116 (50), p.12280-12298
Hauptverfasser:	Giles, Logan J, Grigoropoulos, Alexios, Szilagyi, Robert K
Format:	Artikel
Sprache:	eng
Schlagworte:	Biomimetic Materials - chemistry Biomimetics Bonding Carbon - chemistry Covalence Electronic structure Hydrogenase - chemistry Iron - chemistry Iron-Sulfur Proteins - chemistry Ligands Models, Molecular Molecular Conformation Molecular orbitals Organometallic Compounds - chemistry Oxygen - chemistry Spectra Uncertainty X-Ray Absorption Spectroscopy X-rays
Online-Zugang:	Volltext
Tags:	Tag hinzufügen Keine Tags, Fügen Sie den ersten Tag hinzu!

Schreiben Sie den ersten Kommentar!