Investigation of microstructure and conducting mechanism of nanocomposite polymeric electrolytes with rectorite clay by PALS
Polymeric electrolytes with different modified organic nanoretorite (OREC) content have been prepared. Measurements of the structural transition, the positron annihilation lifetime, free volume and ionic conductivity as a function of the OREC content and the temperature have been performed. Accordin...
Gespeichert in:
| Veröffentlicht in: | Journal of physics. Conference series 2013-01, Vol.443 (1), p.12049-4 |
|---|---|
| Hauptverfasser: | , , , , , |
| Format: | Artikel |
| Sprache: | eng |
| Schlagworte: | |
| Online-Zugang: | Volltext |
| Tags: |
Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
|
| container_end_page | 4 |
|---|---|
| container_issue | 1 |
| container_start_page | 12049 |
| container_title | Journal of physics. Conference series |
| container_volume | 443 |
| creator | Gao, S Gong, J Yan, X L Xue, G B Zhong, J Wang, B |
| description | Polymeric electrolytes with different modified organic nanoretorite (OREC) content have been prepared. Measurements of the structural transition, the positron annihilation lifetime, free volume and ionic conductivity as a function of the OREC content and the temperature have been performed. According to the variations of the ortho-positronium (o-Ps) lifetimes with temperature, the glass transition temperatures have been determined. A direct relationship between the ionic conductivity and the fractional free volume has been established using based on free volume theory Williams-Landel-Ferry (WLF)equations, implying a free-volume transport mechanism. Our experimental results indicated that the segmental chain motion and ionic migration and diffusion could be explained by the free volume theory. |
| doi_str_mv | 10.1088/1742-6596/443/1/012049 |
| format | Article |
| fullrecord | <record><control><sourceid>proquest_cross</sourceid><recordid>TN_cdi_proquest_miscellaneous_1753477821</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>2577495887</sourcerecordid><originalsourceid>FETCH-LOGICAL-c311t-4c02e3b6196fad2041cd656fe66b67d67ec73be02da7adb6f06d334f512405e83</originalsourceid><addsrcrecordid>eNpdkV9LwzAUxYsoOKdfQQK--DKXNGnSPQ7xz2CgoD6HNL3dMtpkJqlS8MObMhHxvuSe5Mcl95wsuyT4huCynBPB8hkvFnzOGJ2TOSY5ZoujbPL7cPynP83OQthhTFOJSfa1sh8QotmoaJxFrkGd0d6F6Hsdew9I2RppZ-skjd2gDvRWWRO6EbXKOu26vQsmAtq7dujAG42gBR19khEC-jRxi3y6cH6kdKsGVA3oebl-Oc9OGtUGuPg5p9nb_d3r7eNs_fSwul2uZ5oSEmdM4xxoxcmCN6pOyxFd84I3wHnFRc0FaEErwHmthKor3mBeU8qaguQMF1DSaXZ9mLv37r1P68rOBA1tqyy4PkgiCsqEKHOS0Kt_6M713qbfybwQgi2KshSJ4gdqtCp4aOTem075QRIsx1Dk6Lcc_ZYpFEnkIRT6DcdJglI</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>2577495887</pqid></control><display><type>article</type><title>Investigation of microstructure and conducting mechanism of nanocomposite polymeric electrolytes with rectorite clay by PALS</title><source>IOP Publishing Free Content</source><source>Elektronische Zeitschriftenbibliothek - Frei zugängliche E-Journals</source><source>IOPscience extra</source><source>Alma/SFX Local Collection</source><source>Free Full-Text Journals in Chemistry</source><creator>Gao, S ; Gong, J ; Yan, X L ; Xue, G B ; Zhong, J ; Wang, B</creator><creatorcontrib>Gao, S ; Gong, J ; Yan, X L ; Xue, G B ; Zhong, J ; Wang, B</creatorcontrib><description>Polymeric electrolytes with different modified organic nanoretorite (OREC) content have been prepared. Measurements of the structural transition, the positron annihilation lifetime, free volume and ionic conductivity as a function of the OREC content and the temperature have been performed. According to the variations of the ortho-positronium (o-Ps) lifetimes with temperature, the glass transition temperatures have been determined. A direct relationship between the ionic conductivity and the fractional free volume has been established using based on free volume theory Williams-Landel-Ferry (WLF)equations, implying a free-volume transport mechanism. Our experimental results indicated that the segmental chain motion and ionic migration and diffusion could be explained by the free volume theory.</description><identifier>ISSN: 1742-6596</identifier><identifier>ISSN: 1742-6588</identifier><identifier>EISSN: 1742-6596</identifier><identifier>DOI: 10.1088/1742-6596/443/1/012049</identifier><language>eng</language><publisher>Bristol: IOP Publishing</publisher><subject>Conducting polymers ; Diffusion ; Electrolytes ; Ferries ; Glass transition temperature ; Ion currents ; Ion migration ; Ionic conductivity ; Ions ; Microstructure ; Migration ; Nanocomposites ; Nanostructure ; Physics ; Positron annihilation ; Positronium ; Transport</subject><ispartof>Journal of physics. Conference series, 2013-01, Vol.443 (1), p.12049-4</ispartof><rights>2013. This work is published under http://creativecommons.org/licenses/by/3.0/ (the “License”). Notwithstanding the ProQuest Terms and Conditions, you may use this content in accordance with the terms of the License.</rights><lds50>peer_reviewed</lds50><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed><cites>FETCH-LOGICAL-c311t-4c02e3b6196fad2041cd656fe66b67d67ec73be02da7adb6f06d334f512405e83</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,780,784,27924,27925</link.rule.ids></links><search><creatorcontrib>Gao, S</creatorcontrib><creatorcontrib>Gong, J</creatorcontrib><creatorcontrib>Yan, X L</creatorcontrib><creatorcontrib>Xue, G B</creatorcontrib><creatorcontrib>Zhong, J</creatorcontrib><creatorcontrib>Wang, B</creatorcontrib><title>Investigation of microstructure and conducting mechanism of nanocomposite polymeric electrolytes with rectorite clay by PALS</title><title>Journal of physics. Conference series</title><description>Polymeric electrolytes with different modified organic nanoretorite (OREC) content have been prepared. Measurements of the structural transition, the positron annihilation lifetime, free volume and ionic conductivity as a function of the OREC content and the temperature have been performed. According to the variations of the ortho-positronium (o-Ps) lifetimes with temperature, the glass transition temperatures have been determined. A direct relationship between the ionic conductivity and the fractional free volume has been established using based on free volume theory Williams-Landel-Ferry (WLF)equations, implying a free-volume transport mechanism. Our experimental results indicated that the segmental chain motion and ionic migration and diffusion could be explained by the free volume theory.</description><subject>Conducting polymers</subject><subject>Diffusion</subject><subject>Electrolytes</subject><subject>Ferries</subject><subject>Glass transition temperature</subject><subject>Ion currents</subject><subject>Ion migration</subject><subject>Ionic conductivity</subject><subject>Ions</subject><subject>Microstructure</subject><subject>Migration</subject><subject>Nanocomposites</subject><subject>Nanostructure</subject><subject>Physics</subject><subject>Positron annihilation</subject><subject>Positronium</subject><subject>Transport</subject><issn>1742-6596</issn><issn>1742-6588</issn><issn>1742-6596</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2013</creationdate><recordtype>article</recordtype><sourceid>ABUWG</sourceid><sourceid>AFKRA</sourceid><sourceid>AZQEC</sourceid><sourceid>BENPR</sourceid><sourceid>CCPQU</sourceid><sourceid>DWQXO</sourceid><recordid>eNpdkV9LwzAUxYsoOKdfQQK--DKXNGnSPQ7xz2CgoD6HNL3dMtpkJqlS8MObMhHxvuSe5Mcl95wsuyT4huCynBPB8hkvFnzOGJ2TOSY5ZoujbPL7cPynP83OQthhTFOJSfa1sh8QotmoaJxFrkGd0d6F6Hsdew9I2RppZ-skjd2gDvRWWRO6EbXKOu26vQsmAtq7dujAG42gBR19khEC-jRxi3y6cH6kdKsGVA3oebl-Oc9OGtUGuPg5p9nb_d3r7eNs_fSwul2uZ5oSEmdM4xxoxcmCN6pOyxFd84I3wHnFRc0FaEErwHmthKor3mBeU8qaguQMF1DSaXZ9mLv37r1P68rOBA1tqyy4PkgiCsqEKHOS0Kt_6M713qbfybwQgi2KshSJ4gdqtCp4aOTem075QRIsx1Dk6Lcc_ZYpFEnkIRT6DcdJglI</recordid><startdate>20130101</startdate><enddate>20130101</enddate><creator>Gao, S</creator><creator>Gong, J</creator><creator>Yan, X L</creator><creator>Xue, G B</creator><creator>Zhong, J</creator><creator>Wang, B</creator><general>IOP Publishing</general><scope>AAYXX</scope><scope>CITATION</scope><scope>8FD</scope><scope>8FE</scope><scope>8FG</scope><scope>ABUWG</scope><scope>AFKRA</scope><scope>ARAPS</scope><scope>AZQEC</scope><scope>BENPR</scope><scope>BGLVJ</scope><scope>CCPQU</scope><scope>DWQXO</scope><scope>H8D</scope><scope>HCIFZ</scope><scope>L7M</scope><scope>P5Z</scope><scope>P62</scope><scope>PIMPY</scope><scope>PQEST</scope><scope>PQQKQ</scope><scope>PQUKI</scope><scope>PRINS</scope><scope>7SP</scope><scope>7U5</scope><scope>8BQ</scope><scope>JG9</scope></search><sort><creationdate>20130101</creationdate><title>Investigation of microstructure and conducting mechanism of nanocomposite polymeric electrolytes with rectorite clay by PALS</title><author>Gao, S ; Gong, J ; Yan, X L ; Xue, G B ; Zhong, J ; Wang, B</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c311t-4c02e3b6196fad2041cd656fe66b67d67ec73be02da7adb6f06d334f512405e83</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2013</creationdate><topic>Conducting polymers</topic><topic>Diffusion</topic><topic>Electrolytes</topic><topic>Ferries</topic><topic>Glass transition temperature</topic><topic>Ion currents</topic><topic>Ion migration</topic><topic>Ionic conductivity</topic><topic>Ions</topic><topic>Microstructure</topic><topic>Migration</topic><topic>Nanocomposites</topic><topic>Nanostructure</topic><topic>Physics</topic><topic>Positron annihilation</topic><topic>Positronium</topic><topic>Transport</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Gao, S</creatorcontrib><creatorcontrib>Gong, J</creatorcontrib><creatorcontrib>Yan, X L</creatorcontrib><creatorcontrib>Xue, G B</creatorcontrib><creatorcontrib>Zhong, J</creatorcontrib><creatorcontrib>Wang, B</creatorcontrib><collection>CrossRef</collection><collection>Technology Research Database</collection><collection>ProQuest SciTech Collection</collection><collection>ProQuest Technology Collection</collection><collection>ProQuest Central (Alumni Edition)</collection><collection>ProQuest Central UK/Ireland</collection><collection>Advanced Technologies & Aerospace Collection</collection><collection>ProQuest Central Essentials</collection><collection>ProQuest Central</collection><collection>Technology Collection</collection><collection>ProQuest One Community College</collection><collection>ProQuest Central Korea</collection><collection>Aerospace Database</collection><collection>SciTech Premium Collection</collection><collection>Advanced Technologies Database with Aerospace</collection><collection>Advanced Technologies & Aerospace Database</collection><collection>ProQuest Advanced Technologies & Aerospace Collection</collection><collection>Publicly Available Content Database</collection><collection>ProQuest One Academic Eastern Edition (DO NOT USE)</collection><collection>ProQuest One Academic</collection><collection>ProQuest One Academic UKI Edition</collection><collection>ProQuest Central China</collection><collection>Electronics & Communications Abstracts</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>METADEX</collection><collection>Materials Research Database</collection><jtitle>Journal of physics. Conference series</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Gao, S</au><au>Gong, J</au><au>Yan, X L</au><au>Xue, G B</au><au>Zhong, J</au><au>Wang, B</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Investigation of microstructure and conducting mechanism of nanocomposite polymeric electrolytes with rectorite clay by PALS</atitle><jtitle>Journal of physics. Conference series</jtitle><date>2013-01-01</date><risdate>2013</risdate><volume>443</volume><issue>1</issue><spage>12049</spage><epage>4</epage><pages>12049-4</pages><issn>1742-6596</issn><issn>1742-6588</issn><eissn>1742-6596</eissn><abstract>Polymeric electrolytes with different modified organic nanoretorite (OREC) content have been prepared. Measurements of the structural transition, the positron annihilation lifetime, free volume and ionic conductivity as a function of the OREC content and the temperature have been performed. According to the variations of the ortho-positronium (o-Ps) lifetimes with temperature, the glass transition temperatures have been determined. A direct relationship between the ionic conductivity and the fractional free volume has been established using based on free volume theory Williams-Landel-Ferry (WLF)equations, implying a free-volume transport mechanism. Our experimental results indicated that the segmental chain motion and ionic migration and diffusion could be explained by the free volume theory.</abstract><cop>Bristol</cop><pub>IOP Publishing</pub><doi>10.1088/1742-6596/443/1/012049</doi><tpages>4</tpages><oa>free_for_read</oa></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 1742-6596 |
| ispartof | Journal of physics. Conference series, 2013-01, Vol.443 (1), p.12049-4 |
| issn | 1742-6596 1742-6588 1742-6596 |
| language | eng |
| recordid | cdi_proquest_miscellaneous_1753477821 |
| source | IOP Publishing Free Content; Elektronische Zeitschriftenbibliothek - Frei zugängliche E-Journals; IOPscience extra; Alma/SFX Local Collection; Free Full-Text Journals in Chemistry |
| subjects | Conducting polymers Diffusion Electrolytes Ferries Glass transition temperature Ion currents Ion migration Ionic conductivity Ions Microstructure Migration Nanocomposites Nanostructure Physics Positron annihilation Positronium Transport |
| title | Investigation of microstructure and conducting mechanism of nanocomposite polymeric electrolytes with rectorite clay by PALS |
| url | https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2025-01-06T22%3A01%3A20IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-proquest_cross&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Investigation%20of%20microstructure%20and%20conducting%20mechanism%20of%20nanocomposite%20polymeric%20electrolytes%20with%20rectorite%20clay%20by%20PALS&rft.jtitle=Journal%20of%20physics.%20Conference%20series&rft.au=Gao,%20S&rft.date=2013-01-01&rft.volume=443&rft.issue=1&rft.spage=12049&rft.epage=4&rft.pages=12049-4&rft.issn=1742-6596&rft.eissn=1742-6596&rft_id=info:doi/10.1088/1742-6596/443/1/012049&rft_dat=%3Cproquest_cross%3E2577495887%3C/proquest_cross%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_pqid=2577495887&rft_id=info:pmid/&rfr_iscdi=true |