Proteogenic Amino Acids: Chiral and Racemic Crystal Packings and Stabilities

Crystal structures of chiral and racemic proteogenic amino acids are compared, over a database of 40 crystal structures and 20 chiral-racemic pairs. Wallach’s rule does not apply. Solubility data show that the racemates tend to be slightly more stable than their chiral counterparts. Lattice energies...

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Veröffentlicht in:	The journal of physical chemistry. B 2012-06, Vol.116 (23), p.6740-6750
Hauptverfasser:	Dunitz, J. D, Gavezzotti, A
Format:	Artikel
Sprache:	eng
Schlagworte:	Amino acids Amino Acids - chemistry Crystal structure Crystals Density Hydrogen Bonding Mathematical analysis Models, Molecular Molecular Structure Quantum Theory Solubility Stability
Online-Zugang:	Volltext
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