Infrared Probing of 4-Azidoproline Conformations Modulated by Azido Configurations

4-Azidoproline (Azp) can tune the stability of the polyproline II (PII) conformation in collagen. The azido group in the 4R and 4S configurations stabilizes and destabilizes the PII conformation, respectively. To obtain insights into the dependence of the conformational stability on the azido config...

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Veröffentlicht in:	The journal of physical chemistry. B 2012-05, Vol.116 (17), p.5097-5110
Hauptverfasser:	Lee, Kyung-Koo, Park, Kwang-Hee, Joo, Cheonik, Kwon, Hyeok-Jun, Jeon, Jonggu, Jung, Hyeon-Il, Park, Sungnam, Han, Hogyu, Cho, Minhaeng
Format:	Artikel
Sprache:	eng
Schlagworte:	Amides - chemistry Azides - chemistry B: Biophysical Chemistry and Biomolecules Derivatives Esters Infrared radiation Mathematical analysis Molecular Conformation Proline Proline - analogs & derivatives Proline - chemistry Quantum Theory Spectra Spectroscopy Spectroscopy, Fourier Transform Infrared Stability Stereoisomerism
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