Direct Observation of the Transition-State Region in the Photodissociation of CH3I by Femtosecond Extreme Ultraviolet Transient Absorption Spectroscopy

Femtosecond extreme ultraviolet (XUV) pulses produced by high harmonic generation are used to probe the transition-state region in the 266 nm photodissociation of CH3I by the real-time evolution of core-to-valence transitions near the iodine N-edge at 45–60 eV. During C–I bond breaking, new core-to-...

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Veröffentlicht in:	The journal of physical chemistry letters 2015-12, Vol.6 (24), p.5072-5077
Hauptverfasser:	Attar, Andrew R, Bhattacherjee, Aditi, Leone, Stephen R
Format:	Artikel
Sprache:	eng
Online-Zugang:	Volltext
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