Composition Dependence of the Na+ Ion Conductivity in 0.5Na2S + 0.5[xGeS2 + (1 – x)PS5/2] Mixed Glass Former Glasses: A Structural Interpretation of a Negative Mixed Glass Former Effect

A negative mixed glass former effect (MGFE) in the Na+ ion conductivity of glass has been found in 0.5Na2S + 0.5­[xGeS2 + (1 – x)­PS5/2] glasses where the Na+ ion conductivity is significantly smaller for all of the ternary glasses than either of the binary end-member glasses. The minimum conductivi...

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Veröffentlicht in:The journal of physical chemistry. B 2015-12, Vol.119 (51), p.15738-15751
Hauptverfasser: Martin, Steve W, Bischoff, Christian, Schuller, Katherine
Format: Artikel
Sprache:eng
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