Circular dichroism and circularly polarized luminescence triggered by self-assembly of tris(phenylisoxazolyl)benzenes possessing a perylenebisimide moiety

Circular dichroism and circularly polarized luminescence triggered by self-assembly of tris(phenylisoxazolyl)benzenes possessing a perylenebisimide moiety

Chiral tris(phenylisoxazolyl)benzenes possessing a perylenebisimide moiety assembled to form helical stacks. The self-assembling behavior of the helical stacks responded to changes in solvent properties, temperature, and concentration. Strong circular dichroism (CD) and circularly polarized luminesc...

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Veröffentlicht in:Chemical communications (Cambridge, England) England), 2012-01, Vol.48 (48), p.6025-6027
Hauptverfasser: Ikeda, Toshiaki, Masuda, Tetsuya, Hirao, Takehiro, Yuasa, Junpei, Tsumatori, Hiroyuki, Kawai, Tsuyoshi, Haino, Takeharu
Format: Artikel
Sprache:eng
Schlagworte:
Circularity
Dichroism
Helical
Luminescence
Self assembly
Solvents
Stacks
Stimuli
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container_end_page 6027
container_issue 48
container_start_page 6025
container_title Chemical communications (Cambridge, England)
container_volume 48
creator Ikeda, Toshiaki
Masuda, Tetsuya
Hirao, Takehiro
Yuasa, Junpei
Tsumatori, Hiroyuki
Kawai, Tsuyoshi
Haino, Takeharu
description Chiral tris(phenylisoxazolyl)benzenes possessing a perylenebisimide moiety assembled to form helical stacks. The self-assembling behavior of the helical stacks responded to changes in solvent properties, temperature, and concentration. Strong circular dichroism (CD) and circularly polarized luminescence (CPL) of their assemblies were displayed, and were controlled by external stimuli.
doi_str_mv 10.1039/c2cc31512b
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source Royal Society Of Chemistry Journals 2008-; Alma/SFX Local Collection
subjects Circularity
Dichroism
Helical
Luminescence
Self assembly
Solvents
Stacks
Stimuli
title Circular dichroism and circularly polarized luminescence triggered by self-assembly of tris(phenylisoxazolyl)benzenes possessing a perylenebisimide moiety
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