Determination of the kinetics underlying the pKa shift for the 2-aminoanthracenium cation binding with cucurbit[7]uril

The binding dynamics of the 2-aminoanthracenium cation (AH(+)) and 2-aminoanthracene (A) with cucurbit[7]uril (CB[7]) was studied using stopped-flow experiments. The kinetics was followed by measuring the fluorescence changes over time for AH(+) and A, which emit at different wavelengths. The studie...

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Veröffentlicht in:	Faraday discussions 2015, Vol.185, p.381-398
Hauptverfasser:	Thomas, Suma S, Bohne, Cornelia
Format:	Artikel
Sprache:	eng
Schlagworte:	Amines - chemistry Anthracenes - chemistry Bridged-Ring Compounds - chemistry Cations - chemistry Hydrogen-Ion Concentration Imidazoles - chemistry Kinetics Molecular Structure
Online-Zugang:	Volltext
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