Halide coordinated homoleptic [Fe4S4X4](2-) and heteroleptic [Fe4S4X2Y2](2-) clusters (X, Y = Cl, Br, I)--alternative preparations, structural analogies and spectroscopic properties in solution and solid state

New facile methods to prepare iron sulphur halide clusters [Fe4S4X4](2-) from [Fe(CO)5] and elemental sulphur were elaborated. Reactions of ferrous precursors like tetrahalidoferrates(ii) or simple ferrous halides with [Fe(CO)5] and sulphur turned out to be efficient methods to prepare homoleptic [F...

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Veröffentlicht in:	Dalton transactions : an international journal of inorganic chemistry 2016-01, Vol.45 (1), p.361-375
Hauptverfasser:	Schüren, Andreas O, Gramm, Verena K, Dürr, Maximilian, Foi, Ana, Ivanović-Burmazović, Ivana, Doctorovich, Fabio, Ruschewitz, Uwe, Klein, Axel
Format:	Artikel
Sprache:	eng
Online-Zugang:	Volltext
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