Performance of selected anion exchange resins for the treatment of a high DOC content surface water
The objective of this study was first to compare the performance of four strong anion exchange resins (AERs) (MIEX ® from Orica Pty Ltd, DOWEX-11 ® and DOWEX-MSA ® from DOW chemical and IRA-938 ® from Rohm and Haas) for their application in drinking water treatment (natural organic matter (NOM), min...
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| Veröffentlicht in: | Water research (Oxford) 2005-05, Vol.39 (9), p.1699-1708 |
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| creator | Humbert, Hugues Gallard, Hervé Suty, Hervé Croué, Jean-Philippe |
| description | The objective of this study was first to compare the performance of four strong anion exchange resins (AERs) (MIEX
® from Orica Pty Ltd, DOWEX-11
® and DOWEX-MSA
® from DOW chemical and IRA-938
® from Rohm and Haas) for their application in drinking water treatment (natural organic matter (NOM), mineral anions (nitrate, sulfate and bromide) and pesticide removal) using bench-scale experimental procedures on a high DOC content surface water. The efficiency of MIEX
® for NOM and mineral anions removal was furthermore evaluated using bench-scale dose-response experiments on raw, clarified and post-ozonated waters. NOM removal was assessed using the measurement of dissolved organic carbon (DOC), UV absorbance at 254
nm (UV
254) and the use of high-performance size exclusion chromatography with UV (HPSEC/UV) and fluorescence detection (HPSEC/FLUO).
The MIEX
® and IRA938
® anionic resins exhibit a faster removal of NOM and mineral anions compared to the DOWEX11
® and MSA
® AERs. All the resins were found to be very effective with similar performances after 30 to 45
min of contact time. As expected, only limited sorption of atrazine and isoproturon (
C
0=1
μg/L) occurred with MIEX
®, DOWEX11
® and MSA
® AERs. MIEX
® resin proved to be very efficient in eliminating NOM of high-molecular weight but also a large part of the smallest UV absorbing organic compounds which were refractory to coagulation/flocculation treatment. Remaining DOC levels after 30
min of contact with MIEX
® were found similar in raw water, clarified water and even post-ozonated water implying no DOC benefit can be gained by employing conventional treatment prior to MIEX
® treatment. Removal of bromide (initial concentration 110
μg/L) was also observed and ranged from 30% to 65% for resin dose increasing from 2 to 8
mL/L. |
| doi_str_mv | 10.1016/j.watres.2005.02.008 |
| format | Article |
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® from Orica Pty Ltd, DOWEX-11
® and DOWEX-MSA
® from DOW chemical and IRA-938
® from Rohm and Haas) for their application in drinking water treatment (natural organic matter (NOM), mineral anions (nitrate, sulfate and bromide) and pesticide removal) using bench-scale experimental procedures on a high DOC content surface water. The efficiency of MIEX
® for NOM and mineral anions removal was furthermore evaluated using bench-scale dose-response experiments on raw, clarified and post-ozonated waters. NOM removal was assessed using the measurement of dissolved organic carbon (DOC), UV absorbance at 254
nm (UV
254) and the use of high-performance size exclusion chromatography with UV (HPSEC/UV) and fluorescence detection (HPSEC/FLUO).
The MIEX
® and IRA938
® anionic resins exhibit a faster removal of NOM and mineral anions compared to the DOWEX11
® and MSA
® AERs. All the resins were found to be very effective with similar performances after 30 to 45
min of contact time. As expected, only limited sorption of atrazine and isoproturon (
C
0=1
μg/L) occurred with MIEX
®, DOWEX11
® and MSA
® AERs. MIEX
® resin proved to be very efficient in eliminating NOM of high-molecular weight but also a large part of the smallest UV absorbing organic compounds which were refractory to coagulation/flocculation treatment. Remaining DOC levels after 30
min of contact with MIEX
® were found similar in raw water, clarified water and even post-ozonated water implying no DOC benefit can be gained by employing conventional treatment prior to MIEX
® treatment. Removal of bromide (initial concentration 110
μg/L) was also observed and ranged from 30% to 65% for resin dose increasing from 2 to 8
mL/L.</description><identifier>ISSN: 0043-1354</identifier><identifier>EISSN: 1879-2448</identifier><identifier>DOI: 10.1016/j.watres.2005.02.008</identifier><identifier>PMID: 15899268</identifier><identifier>CODEN: WATRAG</identifier><language>eng</language><publisher>Oxford: Elsevier Ltd</publisher><subject><![CDATA[Adsorption ; Anion Exchange Resins ; Applied sciences ; Atrazine - isolation & purification ; Biological and medical sciences ; Biotechnology ; Bromide removal ; Bromides - isolation & purification ; Carbamates ; Carbon - isolation & purification ; Chlorides - isolation & purification ; dissolved organic carbon ; drinking water ; Drinking water treatment ; Environment and pollution ; Exact sciences and technology ; Fundamental and applied biological sciences. Psychology ; Herbicides - isolation & purification ; Humic Substances ; Imidazoles ; Industrial applications and implications. Economical aspects ; MIEX ; Nitrates - isolation & purification ; NOM removal ; Other industrial wastes. Sewage sludge ; Pesticide removal ; pesticides ; Phenylurea Compounds - isolation & purification ; Pollution ; Raw and treated waters ; Resins, Synthetic ; Sulfates - isolation & purification ; Time Factors ; Wastes ; Water Pollutants, Chemical - isolation & purification ; water pollution ; Water Purification - methods ; water quality ; Water Supply ; water treatment ; Water treatment and pollution]]></subject><ispartof>Water research (Oxford), 2005-05, Vol.39 (9), p.1699-1708</ispartof><rights>2005 Elsevier Ltd</rights><rights>2005 INIST-CNRS</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c542t-ec66bc51e3da73bb9ba6bd9a08c6a35588a47a0c9c5e00df9f5e61ade1047c0a3</citedby><cites>FETCH-LOGICAL-c542t-ec66bc51e3da73bb9ba6bd9a08c6a35588a47a0c9c5e00df9f5e61ade1047c0a3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktohtml>$$Uhttps://www.sciencedirect.com/science/article/pii/S0043135405000795$$EHTML$$P50$$Gelsevier$$H</linktohtml><link.rule.ids>314,776,780,3537,27901,27902,65534</link.rule.ids><backlink>$$Uhttp://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&idt=16811059$$DView record in Pascal Francis$$Hfree_for_read</backlink><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/15899268$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>Humbert, Hugues</creatorcontrib><creatorcontrib>Gallard, Hervé</creatorcontrib><creatorcontrib>Suty, Hervé</creatorcontrib><creatorcontrib>Croué, Jean-Philippe</creatorcontrib><title>Performance of selected anion exchange resins for the treatment of a high DOC content surface water</title><title>Water research (Oxford)</title><addtitle>Water Res</addtitle><description>The objective of this study was first to compare the performance of four strong anion exchange resins (AERs) (MIEX
® from Orica Pty Ltd, DOWEX-11
® and DOWEX-MSA
® from DOW chemical and IRA-938
® from Rohm and Haas) for their application in drinking water treatment (natural organic matter (NOM), mineral anions (nitrate, sulfate and bromide) and pesticide removal) using bench-scale experimental procedures on a high DOC content surface water. The efficiency of MIEX
® for NOM and mineral anions removal was furthermore evaluated using bench-scale dose-response experiments on raw, clarified and post-ozonated waters. NOM removal was assessed using the measurement of dissolved organic carbon (DOC), UV absorbance at 254
nm (UV
254) and the use of high-performance size exclusion chromatography with UV (HPSEC/UV) and fluorescence detection (HPSEC/FLUO).
The MIEX
® and IRA938
® anionic resins exhibit a faster removal of NOM and mineral anions compared to the DOWEX11
® and MSA
® AERs. All the resins were found to be very effective with similar performances after 30 to 45
min of contact time. As expected, only limited sorption of atrazine and isoproturon (
C
0=1
μg/L) occurred with MIEX
®, DOWEX11
® and MSA
® AERs. MIEX
® resin proved to be very efficient in eliminating NOM of high-molecular weight but also a large part of the smallest UV absorbing organic compounds which were refractory to coagulation/flocculation treatment. Remaining DOC levels after 30
min of contact with MIEX
® were found similar in raw water, clarified water and even post-ozonated water implying no DOC benefit can be gained by employing conventional treatment prior to MIEX
® treatment. Removal of bromide (initial concentration 110
μg/L) was also observed and ranged from 30% to 65% for resin dose increasing from 2 to 8
mL/L.</description><subject>Adsorption</subject><subject>Anion Exchange Resins</subject><subject>Applied sciences</subject><subject>Atrazine - isolation & purification</subject><subject>Biological and medical sciences</subject><subject>Biotechnology</subject><subject>Bromide removal</subject><subject>Bromides - isolation & purification</subject><subject>Carbamates</subject><subject>Carbon - isolation & purification</subject><subject>Chlorides - isolation & purification</subject><subject>dissolved organic carbon</subject><subject>drinking water</subject><subject>Drinking water treatment</subject><subject>Environment and pollution</subject><subject>Exact sciences and technology</subject><subject>Fundamental and applied biological sciences. Psychology</subject><subject>Herbicides - isolation & purification</subject><subject>Humic Substances</subject><subject>Imidazoles</subject><subject>Industrial applications and implications. Economical aspects</subject><subject>MIEX</subject><subject>Nitrates - isolation & purification</subject><subject>NOM removal</subject><subject>Other industrial wastes. Sewage sludge</subject><subject>Pesticide removal</subject><subject>pesticides</subject><subject>Phenylurea Compounds - isolation & purification</subject><subject>Pollution</subject><subject>Raw and treated waters</subject><subject>Resins, Synthetic</subject><subject>Sulfates - isolation & purification</subject><subject>Time Factors</subject><subject>Wastes</subject><subject>Water Pollutants, Chemical - isolation & purification</subject><subject>water pollution</subject><subject>Water Purification - methods</subject><subject>water quality</subject><subject>Water Supply</subject><subject>water treatment</subject><subject>Water treatment and pollution</subject><issn>0043-1354</issn><issn>1879-2448</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2005</creationdate><recordtype>article</recordtype><sourceid>EIF</sourceid><recordid>eNqFkc1v1DAQxS0EotvCf4DAF7glHTt2El-Q0EIBqVIrlZ6tiTPZ9Sofxc7y8d_XUVbqDU6WrN97M_MeY28E5AJEeXnIf-McKOYSQOcgc4D6GduIujKZVKp-zjYAqshEodUZO4_xAABSFuYlOxO6NkaW9Ya5WwrdFAYcHfGp45F6cjO1HEc_jZz-uD2OO-JpkB8jTyif98TTYJwHGudFg3zvd3v--WbL3TTOy288hg6TY1qRwiv2osM-0uvTe8Hur7782H7Lrm--ft9-us6cVnLOyJVl47SgosWqaBrTYNm0BqF2JRZa1zWqCsEZpwmg7UynqRTYkgBVOcDign1YfR_C9PNIcbaDj476HkeajtGKSlW6kur_oEqkMZBAtYIuTDEG6uxD8AOGv1aAXVqwB7u2YJcWLEibWkiytyf_YzNQ-yQ6xZ6A9ycAo8O-Cyl-H5-4shYCtEncu5XrcLK4C4m5v5MgCkg3J5-F-LgSlIL95SnY6DylMlsfUpG2nfy_d30EvIuxzg</recordid><startdate>20050501</startdate><enddate>20050501</enddate><creator>Humbert, Hugues</creator><creator>Gallard, Hervé</creator><creator>Suty, Hervé</creator><creator>Croué, Jean-Philippe</creator><general>Elsevier Ltd</general><general>Elsevier Science</general><scope>FBQ</scope><scope>IQODW</scope><scope>CGR</scope><scope>CUY</scope><scope>CVF</scope><scope>ECM</scope><scope>EIF</scope><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7ST</scope><scope>C1K</scope><scope>SOI</scope><scope>7QH</scope><scope>7TV</scope><scope>7UA</scope><scope>F1W</scope><scope>H96</scope><scope>L.G</scope></search><sort><creationdate>20050501</creationdate><title>Performance of selected anion exchange resins for the treatment of a high DOC content surface water</title><author>Humbert, Hugues ; Gallard, Hervé ; Suty, Hervé ; Croué, Jean-Philippe</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c542t-ec66bc51e3da73bb9ba6bd9a08c6a35588a47a0c9c5e00df9f5e61ade1047c0a3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2005</creationdate><topic>Adsorption</topic><topic>Anion Exchange Resins</topic><topic>Applied sciences</topic><topic>Atrazine - isolation & purification</topic><topic>Biological and medical sciences</topic><topic>Biotechnology</topic><topic>Bromide removal</topic><topic>Bromides - isolation & purification</topic><topic>Carbamates</topic><topic>Carbon - isolation & purification</topic><topic>Chlorides - isolation & purification</topic><topic>dissolved organic carbon</topic><topic>drinking water</topic><topic>Drinking water treatment</topic><topic>Environment and pollution</topic><topic>Exact sciences and technology</topic><topic>Fundamental and applied biological sciences. Psychology</topic><topic>Herbicides - isolation & purification</topic><topic>Humic Substances</topic><topic>Imidazoles</topic><topic>Industrial applications and implications. Economical aspects</topic><topic>MIEX</topic><topic>Nitrates - isolation & purification</topic><topic>NOM removal</topic><topic>Other industrial wastes. Sewage sludge</topic><topic>Pesticide removal</topic><topic>pesticides</topic><topic>Phenylurea Compounds - isolation & purification</topic><topic>Pollution</topic><topic>Raw and treated waters</topic><topic>Resins, Synthetic</topic><topic>Sulfates - isolation & purification</topic><topic>Time Factors</topic><topic>Wastes</topic><topic>Water Pollutants, Chemical - isolation & purification</topic><topic>water pollution</topic><topic>Water Purification - methods</topic><topic>water quality</topic><topic>Water Supply</topic><topic>water treatment</topic><topic>Water treatment and pollution</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Humbert, Hugues</creatorcontrib><creatorcontrib>Gallard, Hervé</creatorcontrib><creatorcontrib>Suty, Hervé</creatorcontrib><creatorcontrib>Croué, Jean-Philippe</creatorcontrib><collection>AGRIS</collection><collection>Pascal-Francis</collection><collection>Medline</collection><collection>MEDLINE</collection><collection>MEDLINE (Ovid)</collection><collection>MEDLINE</collection><collection>MEDLINE</collection><collection>PubMed</collection><collection>CrossRef</collection><collection>Environment Abstracts</collection><collection>Environmental Sciences and Pollution Management</collection><collection>Environment Abstracts</collection><collection>Aqualine</collection><collection>Pollution Abstracts</collection><collection>Water Resources Abstracts</collection><collection>ASFA: Aquatic Sciences and Fisheries Abstracts</collection><collection>Aquatic Science & Fisheries Abstracts (ASFA) 2: Ocean Technology, Policy & Non-Living Resources</collection><collection>Aquatic Science & Fisheries Abstracts (ASFA) Professional</collection><jtitle>Water research (Oxford)</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Humbert, Hugues</au><au>Gallard, Hervé</au><au>Suty, Hervé</au><au>Croué, Jean-Philippe</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Performance of selected anion exchange resins for the treatment of a high DOC content surface water</atitle><jtitle>Water research (Oxford)</jtitle><addtitle>Water Res</addtitle><date>2005-05-01</date><risdate>2005</risdate><volume>39</volume><issue>9</issue><spage>1699</spage><epage>1708</epage><pages>1699-1708</pages><issn>0043-1354</issn><eissn>1879-2448</eissn><coden>WATRAG</coden><abstract>The objective of this study was first to compare the performance of four strong anion exchange resins (AERs) (MIEX
® from Orica Pty Ltd, DOWEX-11
® and DOWEX-MSA
® from DOW chemical and IRA-938
® from Rohm and Haas) for their application in drinking water treatment (natural organic matter (NOM), mineral anions (nitrate, sulfate and bromide) and pesticide removal) using bench-scale experimental procedures on a high DOC content surface water. The efficiency of MIEX
® for NOM and mineral anions removal was furthermore evaluated using bench-scale dose-response experiments on raw, clarified and post-ozonated waters. NOM removal was assessed using the measurement of dissolved organic carbon (DOC), UV absorbance at 254
nm (UV
254) and the use of high-performance size exclusion chromatography with UV (HPSEC/UV) and fluorescence detection (HPSEC/FLUO).
The MIEX
® and IRA938
® anionic resins exhibit a faster removal of NOM and mineral anions compared to the DOWEX11
® and MSA
® AERs. All the resins were found to be very effective with similar performances after 30 to 45
min of contact time. As expected, only limited sorption of atrazine and isoproturon (
C
0=1
μg/L) occurred with MIEX
®, DOWEX11
® and MSA
® AERs. MIEX
® resin proved to be very efficient in eliminating NOM of high-molecular weight but also a large part of the smallest UV absorbing organic compounds which were refractory to coagulation/flocculation treatment. Remaining DOC levels after 30
min of contact with MIEX
® were found similar in raw water, clarified water and even post-ozonated water implying no DOC benefit can be gained by employing conventional treatment prior to MIEX
® treatment. Removal of bromide (initial concentration 110
μg/L) was also observed and ranged from 30% to 65% for resin dose increasing from 2 to 8
mL/L.</abstract><cop>Oxford</cop><pub>Elsevier Ltd</pub><pmid>15899268</pmid><doi>10.1016/j.watres.2005.02.008</doi><tpages>10</tpages></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 0043-1354 |
| ispartof | Water research (Oxford), 2005-05, Vol.39 (9), p.1699-1708 |
| issn | 0043-1354 1879-2448 |
| language | eng |
| recordid | cdi_proquest_miscellaneous_17475724 |
| source | MEDLINE; Elsevier ScienceDirect Journals |
| subjects | Adsorption Anion Exchange Resins Applied sciences Atrazine - isolation & purification Biological and medical sciences Biotechnology Bromide removal Bromides - isolation & purification Carbamates Carbon - isolation & purification Chlorides - isolation & purification dissolved organic carbon drinking water Drinking water treatment Environment and pollution Exact sciences and technology Fundamental and applied biological sciences. Psychology Herbicides - isolation & purification Humic Substances Imidazoles Industrial applications and implications. Economical aspects MIEX Nitrates - isolation & purification NOM removal Other industrial wastes. Sewage sludge Pesticide removal pesticides Phenylurea Compounds - isolation & purification Pollution Raw and treated waters Resins, Synthetic Sulfates - isolation & purification Time Factors Wastes Water Pollutants, Chemical - isolation & purification water pollution Water Purification - methods water quality Water Supply water treatment Water treatment and pollution |
| title | Performance of selected anion exchange resins for the treatment of a high DOC content surface water |
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