Low-valent iron: an Fe(I) ate compound as a building block for a linear trinuclear Fe cluster

Low-valent iron: an Fe(I) ate compound as a building block for a linear trinuclear Fe cluster

A low-valent trinuclear iron complex with an unusual linear Fe(I)-Fe(II)-Fe(I) unit is presented. It is accessed in a rational approach using a salt metathesis reaction between a new anionic Fe(I) containing heterocycle and FeCl2. Its electronic structure was studied by single crystal XRD analysis,...

Ausführliche Beschreibung

Gespeichert in:
Bibliographische Detailangaben
Veröffentlicht in:Chemical communications (Cambridge, England) England), 2015-09, Vol.51 (73), p.13890-13893
Hauptverfasser: Lichtenberg, C, Viciu, L, Vogt, M, Rodríguez-Lugo, R E, Adelhardt, M, Sutter, J, Khusniyarov, M M, Meyer, K, de Bruin, B, Bill, E, Grützmacher, H
Format: Artikel
Sprache:eng
Schlagworte:
Clusters
Electronic structure
Iron
Magnetic permeability
Metathesis
Mossbauer spectroscopy
Single crystals
X-ray diffraction
Online-Zugang:Volltext
Tags: Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
container_end_page 13893
container_issue 73
container_start_page 13890
container_title Chemical communications (Cambridge, England)
container_volume 51
creator Lichtenberg, C
Viciu, L
Vogt, M
Rodríguez-Lugo, R E
Adelhardt, M
Sutter, J
Khusniyarov, M M
Meyer, K
de Bruin, B
Bill, E
Grützmacher, H
description A low-valent trinuclear iron complex with an unusual linear Fe(I)-Fe(II)-Fe(I) unit is presented. It is accessed in a rational approach using a salt metathesis reaction between a new anionic Fe(I) containing heterocycle and FeCl2. Its electronic structure was studied by single crystal XRD analysis, EPR and Mössbauer spectroscopy, and magnetic susceptibility measurements.
doi_str_mv 10.1039/c5cc04908c
format Article
fullrecord <record><control><sourceid>proquest_cross</sourceid><recordid>TN_cdi_proquest_miscellaneous_1744720757</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>1708161869</sourcerecordid><originalsourceid>FETCH-LOGICAL-c356t-ee9d0aeeb828815cb227ec21da0b4181514f30b6bce2937502e64f517b78886e3</originalsourceid><addsrcrecordid>eNqNkEtLxDAUhYMovjf-AMlShWreSd1JcVQYcKPgRkqS3ko104xJq_jv7fhaezfncPjuWRyEDig5pYSXZ156T0RJjF9D25QrUUhhHtZXXpaF5kJuoZ2cn8l0VJpNtMUUY1RxtY0e5_G9eLMB-gF3Kfbn2PZ4Bkc3x9gOgH1cLOPYN9hmbLEbu9B0_RN2IfoX3MY0haHrwSY8pK4ffVjZ2fQXxjxA2kMbrQ0Z9n90F93PLu-q62J-e3VTXcwLz6UaCoCyIRbAGWYMld4xpsEz2ljiBJ0SKlpOnHIeWMm1JAyUaCXVThtjFPBddPTdu0zxdYQ81IsuewjB9hDHXFMthGZES_0PlBiqqFHlhJ58oz7FnBO09TJ1C5s-akrq1fJ1Javqa_lqgg9_eke3gOYP_Z2afwLGQXw_</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>1708161869</pqid></control><display><type>article</type><title>Low-valent iron: an Fe(I) ate compound as a building block for a linear trinuclear Fe cluster</title><source>Royal Society Of Chemistry Journals</source><source>Alma/SFX Local Collection</source><creator>Lichtenberg, C ; Viciu, L ; Vogt, M ; Rodríguez-Lugo, R E ; Adelhardt, M ; Sutter, J ; Khusniyarov, M M ; Meyer, K ; de Bruin, B ; Bill, E ; Grützmacher, H</creator><creatorcontrib>Lichtenberg, C ; Viciu, L ; Vogt, M ; Rodríguez-Lugo, R E ; Adelhardt, M ; Sutter, J ; Khusniyarov, M M ; Meyer, K ; de Bruin, B ; Bill, E ; Grützmacher, H</creatorcontrib><description>A low-valent trinuclear iron complex with an unusual linear Fe(I)-Fe(II)-Fe(I) unit is presented. It is accessed in a rational approach using a salt metathesis reaction between a new anionic Fe(I) containing heterocycle and FeCl2. Its electronic structure was studied by single crystal XRD analysis, EPR and Mössbauer spectroscopy, and magnetic susceptibility measurements.</description><identifier>ISSN: 1359-7345</identifier><identifier>EISSN: 1364-548X</identifier><identifier>DOI: 10.1039/c5cc04908c</identifier><identifier>PMID: 26221636</identifier><language>eng</language><publisher>England</publisher><subject>Clusters ; Electronic structure ; Iron ; Magnetic permeability ; Metathesis ; Mossbauer spectroscopy ; Single crystals ; X-ray diffraction</subject><ispartof>Chemical communications (Cambridge, England), 2015-09, Vol.51 (73), p.13890-13893</ispartof><lds50>peer_reviewed</lds50><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c356t-ee9d0aeeb828815cb227ec21da0b4181514f30b6bce2937502e64f517b78886e3</citedby><cites>FETCH-LOGICAL-c356t-ee9d0aeeb828815cb227ec21da0b4181514f30b6bce2937502e64f517b78886e3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>315,782,786,27931,27932</link.rule.ids><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/26221636$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>Lichtenberg, C</creatorcontrib><creatorcontrib>Viciu, L</creatorcontrib><creatorcontrib>Vogt, M</creatorcontrib><creatorcontrib>Rodríguez-Lugo, R E</creatorcontrib><creatorcontrib>Adelhardt, M</creatorcontrib><creatorcontrib>Sutter, J</creatorcontrib><creatorcontrib>Khusniyarov, M M</creatorcontrib><creatorcontrib>Meyer, K</creatorcontrib><creatorcontrib>de Bruin, B</creatorcontrib><creatorcontrib>Bill, E</creatorcontrib><creatorcontrib>Grützmacher, H</creatorcontrib><title>Low-valent iron: an Fe(I) ate compound as a building block for a linear trinuclear Fe cluster</title><title>Chemical communications (Cambridge, England)</title><addtitle>Chem Commun (Camb)</addtitle><description>A low-valent trinuclear iron complex with an unusual linear Fe(I)-Fe(II)-Fe(I) unit is presented. It is accessed in a rational approach using a salt metathesis reaction between a new anionic Fe(I) containing heterocycle and FeCl2. Its electronic structure was studied by single crystal XRD analysis, EPR and Mössbauer spectroscopy, and magnetic susceptibility measurements.</description><subject>Clusters</subject><subject>Electronic structure</subject><subject>Iron</subject><subject>Magnetic permeability</subject><subject>Metathesis</subject><subject>Mossbauer spectroscopy</subject><subject>Single crystals</subject><subject>X-ray diffraction</subject><issn>1359-7345</issn><issn>1364-548X</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2015</creationdate><recordtype>article</recordtype><recordid>eNqNkEtLxDAUhYMovjf-AMlShWreSd1JcVQYcKPgRkqS3ko104xJq_jv7fhaezfncPjuWRyEDig5pYSXZ156T0RJjF9D25QrUUhhHtZXXpaF5kJuoZ2cn8l0VJpNtMUUY1RxtY0e5_G9eLMB-gF3Kfbn2PZ4Bkc3x9gOgH1cLOPYN9hmbLEbu9B0_RN2IfoX3MY0haHrwSY8pK4ffVjZ2fQXxjxA2kMbrQ0Z9n90F93PLu-q62J-e3VTXcwLz6UaCoCyIRbAGWYMld4xpsEz2ljiBJ0SKlpOnHIeWMm1JAyUaCXVThtjFPBddPTdu0zxdYQ81IsuewjB9hDHXFMthGZES_0PlBiqqFHlhJ58oz7FnBO09TJ1C5s-akrq1fJ1Javqa_lqgg9_eke3gOYP_Z2afwLGQXw_</recordid><startdate>20150921</startdate><enddate>20150921</enddate><creator>Lichtenberg, C</creator><creator>Viciu, L</creator><creator>Vogt, M</creator><creator>Rodríguez-Lugo, R E</creator><creator>Adelhardt, M</creator><creator>Sutter, J</creator><creator>Khusniyarov, M M</creator><creator>Meyer, K</creator><creator>de Bruin, B</creator><creator>Bill, E</creator><creator>Grützmacher, H</creator><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7X8</scope><scope>7SR</scope><scope>7U5</scope><scope>8BQ</scope><scope>8FD</scope><scope>JG9</scope><scope>L7M</scope></search><sort><creationdate>20150921</creationdate><title>Low-valent iron: an Fe(I) ate compound as a building block for a linear trinuclear Fe cluster</title><author>Lichtenberg, C ; Viciu, L ; Vogt, M ; Rodríguez-Lugo, R E ; Adelhardt, M ; Sutter, J ; Khusniyarov, M M ; Meyer, K ; de Bruin, B ; Bill, E ; Grützmacher, H</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c356t-ee9d0aeeb828815cb227ec21da0b4181514f30b6bce2937502e64f517b78886e3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2015</creationdate><topic>Clusters</topic><topic>Electronic structure</topic><topic>Iron</topic><topic>Magnetic permeability</topic><topic>Metathesis</topic><topic>Mossbauer spectroscopy</topic><topic>Single crystals</topic><topic>X-ray diffraction</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Lichtenberg, C</creatorcontrib><creatorcontrib>Viciu, L</creatorcontrib><creatorcontrib>Vogt, M</creatorcontrib><creatorcontrib>Rodríguez-Lugo, R E</creatorcontrib><creatorcontrib>Adelhardt, M</creatorcontrib><creatorcontrib>Sutter, J</creatorcontrib><creatorcontrib>Khusniyarov, M M</creatorcontrib><creatorcontrib>Meyer, K</creatorcontrib><creatorcontrib>de Bruin, B</creatorcontrib><creatorcontrib>Bill, E</creatorcontrib><creatorcontrib>Grützmacher, H</creatorcontrib><collection>PubMed</collection><collection>CrossRef</collection><collection>MEDLINE - Academic</collection><collection>Engineered Materials Abstracts</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><collection>Advanced Technologies Database with Aerospace</collection><jtitle>Chemical communications (Cambridge, England)</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Lichtenberg, C</au><au>Viciu, L</au><au>Vogt, M</au><au>Rodríguez-Lugo, R E</au><au>Adelhardt, M</au><au>Sutter, J</au><au>Khusniyarov, M M</au><au>Meyer, K</au><au>de Bruin, B</au><au>Bill, E</au><au>Grützmacher, H</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Low-valent iron: an Fe(I) ate compound as a building block for a linear trinuclear Fe cluster</atitle><jtitle>Chemical communications (Cambridge, England)</jtitle><addtitle>Chem Commun (Camb)</addtitle><date>2015-09-21</date><risdate>2015</risdate><volume>51</volume><issue>73</issue><spage>13890</spage><epage>13893</epage><pages>13890-13893</pages><issn>1359-7345</issn><eissn>1364-548X</eissn><abstract>A low-valent trinuclear iron complex with an unusual linear Fe(I)-Fe(II)-Fe(I) unit is presented. It is accessed in a rational approach using a salt metathesis reaction between a new anionic Fe(I) containing heterocycle and FeCl2. Its electronic structure was studied by single crystal XRD analysis, EPR and Mössbauer spectroscopy, and magnetic susceptibility measurements.</abstract><cop>England</cop><pmid>26221636</pmid><doi>10.1039/c5cc04908c</doi><tpages>4</tpages><oa>free_for_read</oa></addata></record>
fulltext fulltext
identifier ISSN: 1359-7345
ispartof Chemical communications (Cambridge, England), 2015-09, Vol.51 (73), p.13890-13893
issn 1359-7345
1364-548X
language eng
recordid cdi_proquest_miscellaneous_1744720757
source Royal Society Of Chemistry Journals; Alma/SFX Local Collection
subjects Clusters
Electronic structure
Iron
Magnetic permeability
Metathesis
Mossbauer spectroscopy
Single crystals
X-ray diffraction
title Low-valent iron: an Fe(I) ate compound as a building block for a linear trinuclear Fe cluster
url https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2024-12-09T05%3A51%3A08IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-proquest_cross&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Low-valent%20iron:%20an%20Fe(I)%20ate%20compound%20as%20a%20building%20block%20for%20a%20linear%20trinuclear%20Fe%20cluster&rft.jtitle=Chemical%20communications%20(Cambridge,%20England)&rft.au=Lichtenberg,%20C&rft.date=2015-09-21&rft.volume=51&rft.issue=73&rft.spage=13890&rft.epage=13893&rft.pages=13890-13893&rft.issn=1359-7345&rft.eissn=1364-548X&rft_id=info:doi/10.1039/c5cc04908c&rft_dat=%3Cproquest_cross%3E1708161869%3C/proquest_cross%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_pqid=1708161869&rft_id=info:pmid/26221636&rfr_iscdi=true