Iridium-catalyzed methylation of indoles and pyrroles using methanol as feedstock

Iridium-catalyzed methylation of indoles and pyrroles using methanol as feedstock

Iridium-catalyzed methylation of indoles and pyrroles using methanol as the methylating agent was achieved. This transformation takes place via a borrowing hydrogen methodology under an air atmosphere, which constitutes a direct route to 3-methyl-indoles and methyl-pyrroles.

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Veröffentlicht in:RSC advances 2015-01, Vol.5 (86), p.70329-70332
Hauptverfasser: Chen, Shu-Jie, Lu, Guo-Ping, Cai, Chun
Format: Artikel
Sprache:eng
Schlagworte:
Atmospheres
Feedstock
Indoles
Methodology
Methyl alcohol
Methylation
Pyrroles
Transformations
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Beschreibung
Zusammenfassung:Iridium-catalyzed methylation of indoles and pyrroles using methanol as the methylating agent was achieved. This transformation takes place via a borrowing hydrogen methodology under an air atmosphere, which constitutes a direct route to 3-methyl-indoles and methyl-pyrroles.
ISSN:2046-2069
2046-2069
DOI:10.1039/C5RA15822B