A new reagent for the synthesis of [26]hexaphyrin: N-sulfonyl aldimine

The selective synthesis of [26]hexaphyrin(1.1.1.1.1.1) has been achieved by the reaction of meso-substituted tripyrrane and N-sulfonyl aldimine. The protocol is simple and requires only a catalytic amount of copper(II) triflate under mild reaction conditions. The selective synthesis of [26]hexaphyri...

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Veröffentlicht in:	Tetrahedron letters 2014-01, Vol.55 (2), p.544-547
Hauptverfasser:	Cinar, Seda, Temelli, Baris, Unaleroglu, Canan
Format:	Artikel
Sprache:	eng
Schlagworte:	Catalysis Catalysts Expanded porphyrin Hexaphyrin N-sulfonyl aldimine Synthesis (chemistry) Tetrahedrons Tripyrrane
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creator	Cinar, Seda Temelli, Baris Unaleroglu, Canan
description	The selective synthesis of [26]hexaphyrin(1.1.1.1.1.1) has been achieved by the reaction of meso-substituted tripyrrane and N-sulfonyl aldimine. The protocol is simple and requires only a catalytic amount of copper(II) triflate under mild reaction conditions. The selective synthesis of [26]hexaphyrin(1.1.1.1.1.1) has been achieved by the reaction of meso-substituted tripyrrane and N-sulfonyl aldimine. The protocol is simple and requires only a catalytic amount of copper(II) triflate under mild reaction conditions.
doi_str_mv	10.1016/j.tetlet.2013.11.101
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subjects	Catalysis Catalysts Expanded porphyrin Hexaphyrin N-sulfonyl aldimine Synthesis (chemistry) Tetrahedrons Tripyrrane
title	A new reagent for the synthesis of [26]hexaphyrin: N-sulfonyl aldimine
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