Silver-Catalyzed Cross-Coupling of Isocyanides and Active Methylene Compounds by a Radical Process

Isocyanides are versatile building blocks, and have been extensively exploited in CH functionalization reactions. However, transition‐metal‐catalyzed direct CH functionalization reactions with isocyanides suffer from over‐insertion of isocyanides. Reported herein is a radical coupling/isomerizatio...

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Veröffentlicht in:	Angewandte Chemie International Edition 2015-09, Vol.54 (36), p.10618-10622
Hauptverfasser:	Liu, Jianquan, Liu, Zhenhua, Liao, Peiqiu, Zhang, Lin, Tu, Tao, Bi, Xihe
Format:	Artikel
Sprache:	eng
Schlagworte:	Bonding Catalysis Chemical reactions Chemicals Coupling (molecular) Cross coupling Economics Insertion isocyanides Isomerization Methylene Radicals Silver Strategy Transformations
Online-Zugang:	Volltext
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