Synthesis and characterisation of a new anion exchangeable layered hydroxyiodide
Lu4O(OH)9I·3H2O is a new member of the anion exchangeable lanthanide hydroxyanion family of materials which has been synthesised hydrothermally. Its structure comprises positively charged [Lu4O(OH)9(H2O)3](+) layers with exchangeable charge balancing iodide anions located in the interlayer gallery....
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| Veröffentlicht in: | Dalton transactions : an international journal of inorganic chemistry 2014-07, Vol.43 (27), p.10451-10455 |
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| container_issue | 27 |
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| container_title | Dalton transactions : an international journal of inorganic chemistry |
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| creator | Southworth, Faye Y Wilson, Claire Coles, Simon J Fogg, Andrew M |
| description | Lu4O(OH)9I·3H2O is a new member of the anion exchangeable lanthanide hydroxyanion family of materials which has been synthesised hydrothermally. Its structure comprises positively charged [Lu4O(OH)9(H2O)3](+) layers with exchangeable charge balancing iodide anions located in the interlayer gallery. It has been found to undergo facile anion exchange reactions with dicarboxylate anions such as succinate and terephthalate at room temperature but reacts less readily with disulfonate anions such as 1,5- and 2,6-naphthalenedisulfonate under the same conditions. At reaction temperatures above 200 °C the cationic inorganic framework Lu3O(OH)6I·2H2O forms instead of the layered phase. |
| doi_str_mv | 10.1039/c4dt00123k |
| format | Article |
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Its structure comprises positively charged [Lu4O(OH)9(H2O)3](+) layers with exchangeable charge balancing iodide anions located in the interlayer gallery. It has been found to undergo facile anion exchange reactions with dicarboxylate anions such as succinate and terephthalate at room temperature but reacts less readily with disulfonate anions such as 1,5- and 2,6-naphthalenedisulfonate under the same conditions. 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At reaction temperatures above 200 °C the cationic inorganic framework Lu3O(OH)6I·2H2O forms instead of the layered phase.</description><subject>Anion exchanging</subject><subject>Balancing</subject><subject>Cationic</subject><subject>Charging</subject><subject>Exchange</subject><subject>Galleries</subject><subject>Interlayers</subject><subject>Iodides</subject><issn>1477-9226</issn><issn>1477-9234</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2014</creationdate><recordtype>article</recordtype><recordid>eNqF0LtOwzAUBmALgWgpLDwAyoiQAvaxHdcjKldRCSTKHDn2CQ2kSbET0bw9KS1dmc7t0xl-Qk4ZvWSU6ysrXEMpA_65R4ZMKBVr4GJ_10MyIEchfFAKQCUckgEIqSlnekheXruqmWMoQmQqF9m58cY26ItgmqKuojqPTFThd39dj7jqRfWOJisxKk2HHl0075yvV11Ru8LhMTnITRnwZFtH5O3udjZ5iKfP94-T62lsuUyaGKQBB6DAGs1ohmgMz13GZb9LlEtylWcwttJo6xApMKEzYFRbRpnKreIjcr75u_T1V4uhSRdFsFiWpsK6DSlTQigqev0_lVxJLcdC9PRiQ62vQ_CYp0tfLIzvUkbTddjpRNzMfsN-6vHZ9m-bLdDt6F-6_AeKkHoz</recordid><startdate>20140721</startdate><enddate>20140721</enddate><creator>Southworth, Faye Y</creator><creator>Wilson, Claire</creator><creator>Coles, Simon J</creator><creator>Fogg, Andrew M</creator><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7X8</scope><scope>7SR</scope><scope>7U5</scope><scope>8BQ</scope><scope>8FD</scope><scope>JG9</scope><scope>L7M</scope></search><sort><creationdate>20140721</creationdate><title>Synthesis and characterisation of a new anion exchangeable layered hydroxyiodide</title><author>Southworth, Faye Y ; Wilson, Claire ; Coles, Simon J ; Fogg, Andrew M</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c356t-25a2d2272ca910beeaa3fdb3522767d6f7fb28c5a9cdee02149b2109c1017fc73</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2014</creationdate><topic>Anion exchanging</topic><topic>Balancing</topic><topic>Cationic</topic><topic>Charging</topic><topic>Exchange</topic><topic>Galleries</topic><topic>Interlayers</topic><topic>Iodides</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Southworth, Faye Y</creatorcontrib><creatorcontrib>Wilson, Claire</creatorcontrib><creatorcontrib>Coles, Simon J</creatorcontrib><creatorcontrib>Fogg, Andrew M</creatorcontrib><collection>PubMed</collection><collection>CrossRef</collection><collection>MEDLINE - Academic</collection><collection>Engineered Materials Abstracts</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><collection>Advanced Technologies Database with Aerospace</collection><jtitle>Dalton transactions : an international journal of inorganic chemistry</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Southworth, Faye Y</au><au>Wilson, Claire</au><au>Coles, Simon J</au><au>Fogg, Andrew M</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Synthesis and characterisation of a new anion exchangeable layered hydroxyiodide</atitle><jtitle>Dalton transactions : an international journal of inorganic chemistry</jtitle><addtitle>Dalton Trans</addtitle><date>2014-07-21</date><risdate>2014</risdate><volume>43</volume><issue>27</issue><spage>10451</spage><epage>10455</epage><pages>10451-10455</pages><issn>1477-9226</issn><eissn>1477-9234</eissn><abstract>Lu4O(OH)9I·3H2O is a new member of the anion exchangeable lanthanide hydroxyanion family of materials which has been synthesised hydrothermally. 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| fulltext | fulltext |
| identifier | ISSN: 1477-9226 |
| ispartof | Dalton transactions : an international journal of inorganic chemistry, 2014-07, Vol.43 (27), p.10451-10455 |
| issn | 1477-9226 1477-9234 |
| language | eng |
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| source | Royal Society Of Chemistry Journals 2008-; Alma/SFX Local Collection |
| subjects | Anion exchanging Balancing Cationic Charging Exchange Galleries Interlayers Iodides |
| title | Synthesis and characterisation of a new anion exchangeable layered hydroxyiodide |
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