Metal-free oxidative lactonization of carbohydrates using molecular iodine

We describe herein the oxidative lactonization of fully or partially protected carbohydrates using molecular iodine. Oxidation of aldose hemiacetals is generally carried out by classical procedures, which are rarely chemo or regioselective. We recently reported an optimized methodology for the oxida...

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Veröffentlicht in:	Tetrahedron 2013-07, Vol.69 (29), p.5880-5883
Hauptverfasser:	Fusaro, Maxime B., Chagnault, Vincent, Josse, Solen, Postel, Denis
Format:	Artikel
Sprache:	eng
Schlagworte:	Amines Carbohydrates Carbohydrates chemistry Iodine Iodine chemistry Lactone Metal-free oxidation Methodology Oxidants Oxidation Oxidative lactonization Oxidizing agents Tetrahedrons
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