Platinum CCC-NHC benzimidazolyl pincer complexes: synthesis, characterization, photostability, and theoretical investigation of a blue-green emitter

The recently reported metallation/transmetallation route for the synthesis of CCC-bis(NHC) pincer ligand architectures was extended to 1,3-bis(3'-(trimethylsilylmethyl)-benzimidizol-1'-yl)benzene. The precursor was metallated with Zr(NMe2)4 and transmetallated to Pt using [Pt(COD)Cl2]. Thi...

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Veröffentlicht in:	Dalton transactions : an international journal of inorganic chemistry 2013-06, Vol.42 (24), p.8820-8826
Hauptverfasser:	Huckaba, Aron J, Cao, Bei, Hollis, T Keith, Valle, Henry U, Kelly, John T, Hammer, Nathan I, Oliver, Allen G, Webster, Charles Edwin
Format:	Artikel
Sprache:	eng
Schlagworte:	Architecture Emission spectra Excitation spectra Ground state Molecular structure Platinum Resists Synthesis (chemistry)
Online-Zugang:	Volltext
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