Synthesis and structures of mononuclear 3,4-bis(trifluoromethyl)pyrrolyl complexes of Rh(I) and Ni(II)

New mononuclear complexes of the 3,4-bis(trifluoromethyl)pyrrolyl ligand (3,4-(CF3)2-Pyr(-)) with Rh(I) and Ni(II) are reported. Reaction of 3,4-(CF3)2-PyrNa with [Rh(COD)Cl]2 produces [Rh(PMe3)3(3,4-(CF3)2-Pyr)] (1) while reaction of 3,4-(CF3)2-PyrH with [Ni(PMe3)2Me2] (2) or [Ni(PMe3)2Ph2] (4) giv...

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Veröffentlicht in:	Dalton transactions : an international journal of inorganic chemistry 2014-11, Vol.43 (43), p.16275-16282
Hauptverfasser:	Rivers, Joseph H, Jones, Richard A
Format:	Artikel
Sprache:	eng
Schlagworte:	Diffraction Ligands Single crystals Spectroscopic analysis Spectroscopy Synthesis (chemistry) X-rays
Online-Zugang:	Volltext
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