New C2-symmetry diols accumulating one stereogenic axis and two stereogenic centers

Herein we report a protocol for the enantioselective synthesis of the three stereoisomers of 1,1′-(1,1′-binaphthalene-2,2′-diyl)bis(2,2,2-trifluoroethanol) and their characterization. These compounds, that combine axial and central chirality, might present interesting properties for enantiorecogniti...

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Veröffentlicht in:	Tetrahedron 2012-11, Vol.68 (47), p.9645-9651
Hauptverfasser:	Mendizabal, Julen, de March, Pedro, Recasens, Josep, Virgili, Albert, Álvarez-Larena, Ángel, Elguero, José, Alkorta, Ibon
Format:	Artikel
Sprache:	eng
Schlagworte:	Asymmetric hydrogen transfer Axial chirality Binaphthalenic compounds C2-Symmetry diols Chemistry Chirality Condensed benzenic and aromatic compounds Diols Exact sciences and technology Organic chemistry Preparations and properties Reduction Stereoselective synthesis Synthesis Tetrahedrons
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