Synthesis and ATRP of novel fluorinated aromatic monomer with pendant sulfonate group
A novel fluorinated monomer bearing sulfopropylate side group was successfully synthesized from 2,3,4,5,6-pentafluorostyrene exploiting the lability of the para-fluorine atom. The monomer was polymerized in controlled manner by aqueous atom transfer radical polymerization yielding well-defined water...
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| Veröffentlicht in: | Journal of fluorine chemistry 2013-05, Vol.149, p.30-35 |
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| container_title | Journal of fluorine chemistry |
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| creator | Dimitrov, Ivaylo Jankova, Katja Hvilsted, Søren |
| description | A novel fluorinated monomer bearing sulfopropylate side group was successfully synthesized from 2,3,4,5,6-pentafluorostyrene exploiting the lability of the para-fluorine atom. The monomer was polymerized in controlled manner by aqueous atom transfer radical polymerization yielding well-defined water-soluble fluorinated aromatic polymers with pendant sulfonate groups on each repeating unit. [Display omitted]
► A fluorinated aromatic monomer with pendant sulfonate group was synthesized. ► The monomer was homopolymerized in controlled manner under aqueous ATRP conditions. ► A diblock copolymer was also obtained. ► The polymers’ thermal properties were evaluated.
Novel, fluorinated monomer with pendant sulfonate group was synthesized utilizing a two-step derivatization of 2,3,4,5,6-pentafluorostyrene (FS). The first step was a nucleophilic substitution of the fluorine atom in para position by hydroxyl group followed by sulfopropylation. The monomer was polymerized under aqueous ATRP conditions to yield phenyl-fluorinated aromatic homopolymer bearing pendant sulfonates on each repeating unit. Furthermore, this polymer was used as macroinitiator for the ATRP of poly(ethylene glycol) methacrylate. The polymers were characterized by 1H NMR, SEC and FTIR analyses. Their thermal properties were evaluated by differential scanning calorimetry and thermal gravimetric analyses. |
| doi_str_mv | 10.1016/j.jfluchem.2013.02.008 |
| format | Article |
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► A fluorinated aromatic monomer with pendant sulfonate group was synthesized. ► The monomer was homopolymerized in controlled manner under aqueous ATRP conditions. ► A diblock copolymer was also obtained. ► The polymers’ thermal properties were evaluated.
Novel, fluorinated monomer with pendant sulfonate group was synthesized utilizing a two-step derivatization of 2,3,4,5,6-pentafluorostyrene (FS). The first step was a nucleophilic substitution of the fluorine atom in para position by hydroxyl group followed by sulfopropylation. The monomer was polymerized under aqueous ATRP conditions to yield phenyl-fluorinated aromatic homopolymer bearing pendant sulfonates on each repeating unit. Furthermore, this polymer was used as macroinitiator for the ATRP of poly(ethylene glycol) methacrylate. The polymers were characterized by 1H NMR, SEC and FTIR analyses. Their thermal properties were evaluated by differential scanning calorimetry and thermal gravimetric analyses.</description><identifier>ISSN: 0022-1139</identifier><identifier>EISSN: 1873-3328</identifier><identifier>DOI: 10.1016/j.jfluchem.2013.02.008</identifier><language>eng</language><publisher>Elsevier B.V</publisher><subject>ATRP ; Differential scanning calorimetry ; Fluorinated monomer ; Fluorination ; Fluorine ; Jewelry ; Monomers ; Polyelectrolyte ; Sulfonates ; Synthesis ; Synthesis (chemistry) ; Thermal properties ; Thermal stability</subject><ispartof>Journal of fluorine chemistry, 2013-05, Vol.149, p.30-35</ispartof><rights>2013 Elsevier B.V.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c345t-e303736891ecc292c033b5a8dcfa308f4143f9766e0a70a9c65b587814c414723</citedby><cites>FETCH-LOGICAL-c345t-e303736891ecc292c033b5a8dcfa308f4143f9766e0a70a9c65b587814c414723</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktohtml>$$Uhttps://dx.doi.org/10.1016/j.jfluchem.2013.02.008$$EHTML$$P50$$Gelsevier$$H</linktohtml><link.rule.ids>314,780,784,3550,27924,27925,45995</link.rule.ids></links><search><creatorcontrib>Dimitrov, Ivaylo</creatorcontrib><creatorcontrib>Jankova, Katja</creatorcontrib><creatorcontrib>Hvilsted, Søren</creatorcontrib><title>Synthesis and ATRP of novel fluorinated aromatic monomer with pendant sulfonate group</title><title>Journal of fluorine chemistry</title><description>A novel fluorinated monomer bearing sulfopropylate side group was successfully synthesized from 2,3,4,5,6-pentafluorostyrene exploiting the lability of the para-fluorine atom. The monomer was polymerized in controlled manner by aqueous atom transfer radical polymerization yielding well-defined water-soluble fluorinated aromatic polymers with pendant sulfonate groups on each repeating unit. [Display omitted]
► A fluorinated aromatic monomer with pendant sulfonate group was synthesized. ► The monomer was homopolymerized in controlled manner under aqueous ATRP conditions. ► A diblock copolymer was also obtained. ► The polymers’ thermal properties were evaluated.
Novel, fluorinated monomer with pendant sulfonate group was synthesized utilizing a two-step derivatization of 2,3,4,5,6-pentafluorostyrene (FS). The first step was a nucleophilic substitution of the fluorine atom in para position by hydroxyl group followed by sulfopropylation. The monomer was polymerized under aqueous ATRP conditions to yield phenyl-fluorinated aromatic homopolymer bearing pendant sulfonates on each repeating unit. Furthermore, this polymer was used as macroinitiator for the ATRP of poly(ethylene glycol) methacrylate. The polymers were characterized by 1H NMR, SEC and FTIR analyses. Their thermal properties were evaluated by differential scanning calorimetry and thermal gravimetric analyses.</description><subject>ATRP</subject><subject>Differential scanning calorimetry</subject><subject>Fluorinated monomer</subject><subject>Fluorination</subject><subject>Fluorine</subject><subject>Jewelry</subject><subject>Monomers</subject><subject>Polyelectrolyte</subject><subject>Sulfonates</subject><subject>Synthesis</subject><subject>Synthesis (chemistry)</subject><subject>Thermal properties</subject><subject>Thermal stability</subject><issn>0022-1139</issn><issn>1873-3328</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2013</creationdate><recordtype>article</recordtype><recordid>eNqFkMtOwzAQRS0EEqXwC8hLNgljO42dHRXiJSGBoF1brjOhrhK72Amof0-qwprVLO69R5pDyCWDnAErrzf5pmkHu8Yu58BEDjwHUEdkwpQUmRBcHZMJAOcZY6I6JWcpbQBAglQTsnzf-X6NySVqfE3ni7dXGhrqwxe2dMSG6LzpsaYmhs70ztIu-NBhpN-uX9Mt-tr4nqahbcK-SD9iGLbn5KQxbcKL3zsly_u7xe1j9vzy8HQ7f86sKGZ9hgKEFKWqGFrLK25BiNXMqNo2RoBqClaIppJliWAkmMqWs9VMScUKO0aSiym5OnC3MXwOmHrduWSxbY3HMCTNZFGU1WhgXy0PVRtDShEbvY2uM3GnGei9R73Rfx713qMGrkeP4_DmMMTxkS-HUSfr0FusXUTb6zq4_xA_dwZ_TA</recordid><startdate>201305</startdate><enddate>201305</enddate><creator>Dimitrov, Ivaylo</creator><creator>Jankova, Katja</creator><creator>Hvilsted, Søren</creator><general>Elsevier B.V</general><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>7U5</scope><scope>8BQ</scope><scope>8FD</scope><scope>JG9</scope><scope>L7M</scope></search><sort><creationdate>201305</creationdate><title>Synthesis and ATRP of novel fluorinated aromatic monomer with pendant sulfonate group</title><author>Dimitrov, Ivaylo ; Jankova, Katja ; Hvilsted, Søren</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c345t-e303736891ecc292c033b5a8dcfa308f4143f9766e0a70a9c65b587814c414723</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2013</creationdate><topic>ATRP</topic><topic>Differential scanning calorimetry</topic><topic>Fluorinated monomer</topic><topic>Fluorination</topic><topic>Fluorine</topic><topic>Jewelry</topic><topic>Monomers</topic><topic>Polyelectrolyte</topic><topic>Sulfonates</topic><topic>Synthesis</topic><topic>Synthesis (chemistry)</topic><topic>Thermal properties</topic><topic>Thermal stability</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Dimitrov, Ivaylo</creatorcontrib><creatorcontrib>Jankova, Katja</creatorcontrib><creatorcontrib>Hvilsted, Søren</creatorcontrib><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><collection>Advanced Technologies Database with Aerospace</collection><jtitle>Journal of fluorine chemistry</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Dimitrov, Ivaylo</au><au>Jankova, Katja</au><au>Hvilsted, Søren</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Synthesis and ATRP of novel fluorinated aromatic monomer with pendant sulfonate group</atitle><jtitle>Journal of fluorine chemistry</jtitle><date>2013-05</date><risdate>2013</risdate><volume>149</volume><spage>30</spage><epage>35</epage><pages>30-35</pages><issn>0022-1139</issn><eissn>1873-3328</eissn><abstract>A novel fluorinated monomer bearing sulfopropylate side group was successfully synthesized from 2,3,4,5,6-pentafluorostyrene exploiting the lability of the para-fluorine atom. The monomer was polymerized in controlled manner by aqueous atom transfer radical polymerization yielding well-defined water-soluble fluorinated aromatic polymers with pendant sulfonate groups on each repeating unit. [Display omitted]
► A fluorinated aromatic monomer with pendant sulfonate group was synthesized. ► The monomer was homopolymerized in controlled manner under aqueous ATRP conditions. ► A diblock copolymer was also obtained. ► The polymers’ thermal properties were evaluated.
Novel, fluorinated monomer with pendant sulfonate group was synthesized utilizing a two-step derivatization of 2,3,4,5,6-pentafluorostyrene (FS). The first step was a nucleophilic substitution of the fluorine atom in para position by hydroxyl group followed by sulfopropylation. The monomer was polymerized under aqueous ATRP conditions to yield phenyl-fluorinated aromatic homopolymer bearing pendant sulfonates on each repeating unit. Furthermore, this polymer was used as macroinitiator for the ATRP of poly(ethylene glycol) methacrylate. The polymers were characterized by 1H NMR, SEC and FTIR analyses. Their thermal properties were evaluated by differential scanning calorimetry and thermal gravimetric analyses.</abstract><pub>Elsevier B.V</pub><doi>10.1016/j.jfluchem.2013.02.008</doi><tpages>6</tpages></addata></record> |
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| ispartof | Journal of fluorine chemistry, 2013-05, Vol.149, p.30-35 |
| issn | 0022-1139 1873-3328 |
| language | eng |
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| source | Access via ScienceDirect (Elsevier) |
| subjects | ATRP Differential scanning calorimetry Fluorinated monomer Fluorination Fluorine Jewelry Monomers Polyelectrolyte Sulfonates Synthesis Synthesis (chemistry) Thermal properties Thermal stability |
| title | Synthesis and ATRP of novel fluorinated aromatic monomer with pendant sulfonate group |
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