Modulating the magnetic properties by structural modification in a family of Co-Ln (Ln = Gd, Dy) molecular aggregates

Two types of heterometallic aggregates of the general formula [(Co(II))3(Co(III))2Ln3(μ3-OH)5(O2C(t)Bu)12(L)2]·2H2O (Ln = Gd(III) (), Dy(III) ()) and [(Co(III))3Ln3(μ3-OH)4(O2C(t)Bu)6(L)3](NO3)2·2CH3CN·2H2O (Ln = Gd(III) (), Dy(III) ()) were successfully isolated in reactions with [Co2(μ-OH2)(O2C(t)...

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Veröffentlicht in:	Dalton transactions : an international journal of inorganic chemistry 2014-10, Vol.43 (39), p.14577-14585
Hauptverfasser:	Sheikh, Javeed Ahmad, Goswami, Soumyabrata, Konar, Sanjit
Format:	Artikel
Sprache:	eng
Schlagworte:	Aggregates Bonding Cubane Displays Distortion Dysprosium Mathematical analysis Stoichiometry
Online-Zugang:	Volltext
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