Synthesis and (spectro)electrochemistry of mixed-valent diferrocenyl-dihydrothiopyran derivatives

Three novel diferrocenyl complexes were prepared and characterised. 2,2-Diferrocenyl-4,5-dimethyl-3,6-dihydro-2H-thiopyran (1, sulphide) was accessible by the hetero-Diels-Alder reaction of diferrocenyl thioketone with 2,3-dimethyl-1,3-butadiene. Stepwise oxidation of 1 gave the respective oxides 2,...

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Veröffentlicht in:	Dalton transactions : an international journal of inorganic chemistry 2015-04, Vol.44 (13), p.6268-6276
Hauptverfasser:	Kowalski, Konrad, Karpowicz, Rafał, Mlostoń, Grzegorz, Miesel, Dominique, Hildebrandt, Alexander, Lang, Heinrich, Czerwieniec, Rafał, Therrien, Bruno
Format:	Artikel
Sprache:	eng
Schlagworte:	Cations Electronics Molecular structure Oxidation Sulfides Sulfones Sulfur Voltammetry
Online-Zugang:	Volltext
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