Two-photon Absorption (TPA) Spectra of Tris(4,7-diphenyl-1,10-phenanthroline)metal(II) Perchlorate

Two-photon Absorption (TPA) Spectra of Tris(4,7-diphenyl-1,10-phenanthroline)metal(II) Perchlorate

Two-photon absorption (TPA) spectra were measured on a dimethyl sulfoxide solution of [M(dpphen)3](ClO4)2 (dpphen: 4,7-diphenyl-1,10-phenanthroline; M = Mn, Co, Ni, Cu, Zn, and Ru). The TPA cross section depended drastically on the central metal(II) ions, in the order Ru- > Co- > Ni- > Mn-...

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Veröffentlicht in:Chemistry letters 2014-04, Vol.43 (4), p.441-441
Hauptverfasser: Moritomo, Hiroki, Nakagawa, Kenta, Sugihara, Hiroyuki, Suzuki, Yasutaka, Kawamata, Jun
Format: Artikel
Sprache:eng
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Cobalt
Copper
Cross sections
Dimethyl sulfoxide
Manganese
Nickel
Photons
Spectra
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container_end_page 441
container_issue 4
container_start_page 441
container_title Chemistry letters
container_volume 43
creator Moritomo, Hiroki
Nakagawa, Kenta
Sugihara, Hiroyuki
Suzuki, Yasutaka
Kawamata, Jun
description Two-photon absorption (TPA) spectra were measured on a dimethyl sulfoxide solution of [M(dpphen)3](ClO4)2 (dpphen: 4,7-diphenyl-1,10-phenanthroline; M = Mn, Co, Ni, Cu, Zn, and Ru). The TPA cross section depended drastically on the central metal(II) ions, in the order Ru- > Co- > Ni- > Mn- > Cu- > Zn complexes. The effects were rationalized in terms of the resonance of photons used for two-photon transition with one-photon absorption band.
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source Oxford University Press Journals All Titles (1996-Current)
subjects Cobalt
Copper
Cross sections
Dimethyl sulfoxide
Manganese
Nickel
Photons
Spectra
title Two-photon Absorption (TPA) Spectra of Tris(4,7-diphenyl-1,10-phenanthroline)metal(II) Perchlorate
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