Evaporation-induced self-assembly of trans-2-aminocyclopentanecarboxylic acid hexamers
In this paper, we report the self-assembly phenomenon of trans-2-aminocyclopentanecarboxylic acid hexamer (ACPC6) by the evaporation-induced self-assembly. The SEM and TEM analyses of the self-assembled 3D molecular architecture revealed the characteristic shape of hollow parallelepiped and its supr...
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| Veröffentlicht in: | Tetrahedron 2012-06, Vol.68 (23), p.4368-4373 |
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| creator | Kwon, Sunbum Kang, Kyungtae Jeon, Aram Park, Ji Hun Choi, Insung S. Lee, Hee-Seung |
| description | In this paper, we report the self-assembly phenomenon of trans-2-aminocyclopentanecarboxylic acid hexamer (ACPC6) by the evaporation-induced self-assembly. The SEM and TEM analyses of the self-assembled 3D molecular architecture revealed the characteristic shape of hollow parallelepiped and its supramolecular chiral expression on surface. A systematic study with the derivatives of ACPC6 showed the effect of the terminal groups of ACPC6 on the particular 3D shape formation. We also found that water molecules played a crucial role in the formation of hollow morphogenesis under the evaporation-induced self-assembly condition, and a plausible formation mechanism was suggested.
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| doi_str_mv | 10.1016/j.tet.2012.02.061 |
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| subjects | Derivatives Evaporation Foldamer Formations Nanostructure Parallelepipeds Self assembly Terminals Three dimensional Transmission electron microscopy β-Peptide |
| title | Evaporation-induced self-assembly of trans-2-aminocyclopentanecarboxylic acid hexamers |
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