Trial for anti-Markovnikov Hydration of 1-Decene Using Platinum Complexes Bearing a PBP Pincer Ligand, Inducing Alkene Isomerization and Decomposition of PBP Ligand

Trial for anti-Markovnikov Hydration of 1-Decene Using Platinum Complexes Bearing a PBP Pincer Ligand, Inducing Alkene Isomerization and Decomposition of PBP Ligand

Mixing of [(PBP)PtCl] complex with 1-decene and H2O afforded isomerized alkenes. Deuterium-labeling experiment indicated the catalytically active hydride species for alkene isomerization formed from water and [(PBP)Pt] complex. Reaction of [(PBP)PtNTf2] with H2O gave a platinum hydride complex havin...

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Veröffentlicht in:Chemistry letters 2014-05, Vol.43 (5), p.664-666
Hauptverfasser: Ogawa, Hayato, Yamashita, Makoto
Format: Artikel
Sprache:eng
Schlagworte:
Alkenes
Cationic
Hydration
Hydrides
Isomerization
Ligands
Olefins
Platinum
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Yamashita, Makoto
description Mixing of [(PBP)PtCl] complex with 1-decene and H2O afforded isomerized alkenes. Deuterium-labeling experiment indicated the catalytically active hydride species for alkene isomerization formed from water and [(PBP)Pt] complex. Reaction of [(PBP)PtNTf2] with H2O gave a platinum hydride complex having PNNP ligand with a loss of boron atom, but the resulting complex showed low catalytic activity. Two types of cationic platinum hydride complexes were suggested as active species for alkene isomerization.
doi_str_mv 10.1246/cl.131208
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source Oxford University Press Journals All Titles (1996-Current)
subjects Alkenes
Cationic
Hydration
Hydrides
Isomerization
Ligands
Olefins
Platinum
title Trial for anti-Markovnikov Hydration of 1-Decene Using Platinum Complexes Bearing a PBP Pincer Ligand, Inducing Alkene Isomerization and Decomposition of PBP Ligand
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