Rhenium complex-catalyzed coupling reaction of enol acetates with alcohols
[Display omitted] The reaction of enol acetates with alcohols in the presence of a catalytic amount of a rhenium complex, such as ReBr(CO)5, produced the corresponding ketones and aldehydes in moderate to good yields. It was suggested that the preparation of an ether, an intermolecular dehydrated pr...
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| Veröffentlicht in: | Tetrahedron letters 2014-10, Vol.55 (44), p.6113-6116 |
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| container_title | Tetrahedron letters |
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| creator | Umeda, Rui Takahashi, Yuuki Nishiyama, Yutaka |
| description | [Display omitted]
The reaction of enol acetates with alcohols in the presence of a catalytic amount of a rhenium complex, such as ReBr(CO)5, produced the corresponding ketones and aldehydes in moderate to good yields. It was suggested that the preparation of an ether, an intermolecular dehydrated product, was the first step of the reaction. |
| doi_str_mv | 10.1016/j.tetlet.2014.09.054 |
| format | Article |
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The reaction of enol acetates with alcohols in the presence of a catalytic amount of a rhenium complex, such as ReBr(CO)5, produced the corresponding ketones and aldehydes in moderate to good yields. It was suggested that the preparation of an ether, an intermolecular dehydrated product, was the first step of the reaction.</description><identifier>ISSN: 0040-4039</identifier><identifier>EISSN: 1873-3581</identifier><identifier>DOI: 10.1016/j.tetlet.2014.09.054</identifier><language>eng</language><publisher>Elsevier Ltd</publisher><subject>Acetates ; Alcohols ; Catalysis ; Chemical reactions ; Enol acetates ; Ethers ; Ketones ; Rhenium ; Tetrahedrons ; α-Alkylated carbonyl compounds</subject><ispartof>Tetrahedron letters, 2014-10, Vol.55 (44), p.6113-6116</ispartof><rights>2014 Elsevier Ltd</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c339t-9981f42796ba6116c173116f4aba2e946cb90eb5211e53a42dfa0bced0fb659f3</citedby><cites>FETCH-LOGICAL-c339t-9981f42796ba6116c173116f4aba2e946cb90eb5211e53a42dfa0bced0fb659f3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktohtml>$$Uhttps://www.sciencedirect.com/science/article/pii/S004040391401555X$$EHTML$$P50$$Gelsevier$$H</linktohtml><link.rule.ids>314,776,780,3537,27901,27902,65306</link.rule.ids></links><search><creatorcontrib>Umeda, Rui</creatorcontrib><creatorcontrib>Takahashi, Yuuki</creatorcontrib><creatorcontrib>Nishiyama, Yutaka</creatorcontrib><title>Rhenium complex-catalyzed coupling reaction of enol acetates with alcohols</title><title>Tetrahedron letters</title><description>[Display omitted]
The reaction of enol acetates with alcohols in the presence of a catalytic amount of a rhenium complex, such as ReBr(CO)5, produced the corresponding ketones and aldehydes in moderate to good yields. It was suggested that the preparation of an ether, an intermolecular dehydrated product, was the first step of the reaction.</description><subject>Acetates</subject><subject>Alcohols</subject><subject>Catalysis</subject><subject>Chemical reactions</subject><subject>Enol acetates</subject><subject>Ethers</subject><subject>Ketones</subject><subject>Rhenium</subject><subject>Tetrahedrons</subject><subject>α-Alkylated carbonyl compounds</subject><issn>0040-4039</issn><issn>1873-3581</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2014</creationdate><recordtype>article</recordtype><recordid>eNp9kE9LxDAQxYMouK5-Aw89emlNmjRtLoIs_kUQRM8hTSdulrRZk1RdP71d6tm5PBjee8z8EDonuCCY8MtNkSA5SEWJCSuwKHDFDtCCNDXNadWQQ7TAmOGcYSqO0UmMGzwNb_ACPb6sYbBjn2nfbx1851ol5XY_0E2bcevs8J4FUDpZP2TeZDB4lykNSSWI2ZdN60w57dfexVN0ZJSLcPanS_R2e_O6us-fnu8eVtdPuaZUpFyIhhhW1oK3ihPCNanpJIapVpUgGNetwNBWJSFQUcXKzijcauiwaXklDF2ii7l3G_zHCDHJ3kYNzqkB_BglqRnjDee0mqxsturgYwxg5DbYXoWdJFju0cmNnNHJPTqJhZzQTbGrOQbTG58WgozawjDdYAPoJDtv_y_4BTWAemw</recordid><startdate>20141029</startdate><enddate>20141029</enddate><creator>Umeda, Rui</creator><creator>Takahashi, Yuuki</creator><creator>Nishiyama, Yutaka</creator><general>Elsevier Ltd</general><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>7U5</scope><scope>8BQ</scope><scope>8FD</scope><scope>JG9</scope><scope>L7M</scope></search><sort><creationdate>20141029</creationdate><title>Rhenium complex-catalyzed coupling reaction of enol acetates with alcohols</title><author>Umeda, Rui ; Takahashi, Yuuki ; Nishiyama, Yutaka</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c339t-9981f42796ba6116c173116f4aba2e946cb90eb5211e53a42dfa0bced0fb659f3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2014</creationdate><topic>Acetates</topic><topic>Alcohols</topic><topic>Catalysis</topic><topic>Chemical reactions</topic><topic>Enol acetates</topic><topic>Ethers</topic><topic>Ketones</topic><topic>Rhenium</topic><topic>Tetrahedrons</topic><topic>α-Alkylated carbonyl compounds</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Umeda, Rui</creatorcontrib><creatorcontrib>Takahashi, Yuuki</creatorcontrib><creatorcontrib>Nishiyama, Yutaka</creatorcontrib><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><collection>Advanced Technologies Database with Aerospace</collection><jtitle>Tetrahedron letters</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Umeda, Rui</au><au>Takahashi, Yuuki</au><au>Nishiyama, Yutaka</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Rhenium complex-catalyzed coupling reaction of enol acetates with alcohols</atitle><jtitle>Tetrahedron letters</jtitle><date>2014-10-29</date><risdate>2014</risdate><volume>55</volume><issue>44</issue><spage>6113</spage><epage>6116</epage><pages>6113-6116</pages><issn>0040-4039</issn><eissn>1873-3581</eissn><abstract>[Display omitted]
The reaction of enol acetates with alcohols in the presence of a catalytic amount of a rhenium complex, such as ReBr(CO)5, produced the corresponding ketones and aldehydes in moderate to good yields. It was suggested that the preparation of an ether, an intermolecular dehydrated product, was the first step of the reaction.</abstract><pub>Elsevier Ltd</pub><doi>10.1016/j.tetlet.2014.09.054</doi><tpages>4</tpages></addata></record> |
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| ispartof | Tetrahedron letters, 2014-10, Vol.55 (44), p.6113-6116 |
| issn | 0040-4039 1873-3581 |
| language | eng |
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| source | Elsevier ScienceDirect Journals Complete |
| subjects | Acetates Alcohols Catalysis Chemical reactions Enol acetates Ethers Ketones Rhenium Tetrahedrons α-Alkylated carbonyl compounds |
| title | Rhenium complex-catalyzed coupling reaction of enol acetates with alcohols |
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