Halogen-Bond-Assisted Guest Inclusion in a Synthetic Cavity

The confined space inside a self‐assembled cage enhanced halogen bonding (XB) between iodoperfluorocarbons (XB donors) and NO3− anions or H2O molecules (XB acceptors), as confirmed by NMR spectroscopy in solution and by X‐ray crystallography in the solid state. The cavity also bound an XB donor–acce...

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Veröffentlicht in:	Angewandte Chemie International Edition 2015-07, Vol.54 (29), p.8411-8414
Hauptverfasser:	Takezawa, Hiroki, Murase, Takashi, Resnati, Giuseppe, Metrangolo, Pierangelo, Fujita, Makoto
Format:	Artikel
Sprache:	eng
Schlagworte:	Anions Bonding Cage Crystallography halocarbon compounds halogen bonding Halogens Holes host-guest interactions molecular recognition NMR NMR spectroscopy Nuclear magnetic resonance self-assembly X-rays
Online-Zugang:	Volltext
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