[bmIm]OH: an efficient basic catalyst for the synthesis of 4H-benzo[d][1,3-]oxazin-4-one derivatives in solvent-free conditions

[Display omitted] Reusable [bmIm]OH was found to be a highly efficient renewable homogenous catalyst for the rapid and convenient synthesis of benzoxazine-4-one derivatives from o-iodobenzoic-acid and benzonitrile at 75°C in moderate to good yields. This methodology provides a facile and straightfor...

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Veröffentlicht in:Tetrahedron letters 2014-10, Vol.55 (44), p.6072-6076
Hauptverfasser: Waseem, Malik Abdul, Shireen, Srivastava, Anjali, Srivastava, Arjita, Rahila, Siddiqui, I.R.
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container_end_page 6076
container_issue 44
container_start_page 6072
container_title Tetrahedron letters
container_volume 55
creator Waseem, Malik Abdul
Shireen
Srivastava, Anjali
Srivastava, Arjita
Rahila
Siddiqui, I.R.
description [Display omitted] Reusable [bmIm]OH was found to be a highly efficient renewable homogenous catalyst for the rapid and convenient synthesis of benzoxazine-4-one derivatives from o-iodobenzoic-acid and benzonitrile at 75°C in moderate to good yields. This methodology provides a facile and straightforward path to construct other related heterocycles in an eco-compatible fashion.
doi_str_mv 10.1016/j.tetlet.2014.09.055
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source Elsevier ScienceDirect Journals Complete - AutoHoldings
subjects [bmIm]OH
Benzonitrile
Benzoxazine-4-one
Catalysts
Construction
Derivatives
Green protocol
Intermolecular heterocyclization
Iodobenzoic acid
Methodology
Reusable
Synthesis (chemistry)
Tetrahedrons
title [bmIm]OH: an efficient basic catalyst for the synthesis of 4H-benzo[d][1,3-]oxazin-4-one derivatives in solvent-free conditions
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