Bis-(2-ethylhexyl) carbamoyl methoxy phenoxy-bis-(2-ethylhexyl) acetamide [BenzoDODA]—first selective extractant for plutonium(IV) recovery (SEPUR) from acidic media

A novel extractant, namely, Benzodioxodiamide (BenzoDODA) has been synthesized and evaluated for its extraction behaviour towards plutonium and other elements present in the spent nuclear fuel. High separation factors for plutonium over other elements were observed, indicating the high selectivity o...

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Veröffentlicht in:Tetrahedron letters 2012-10, Vol.53 (40), p.5434-5436
Hauptverfasser: Ruhela, R., Panja, S., Tomar, B.S., Mahajan, M.A., Sawant, R.M., Tripathi, S.C., Singh, A.K., Gandhi, P.M., Hubli, R.C., Suri, A.K.
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container_end_page 5436
container_issue 40
container_start_page 5434
container_title Tetrahedron letters
container_volume 53
creator Ruhela, R.
Panja, S.
Tomar, B.S.
Mahajan, M.A.
Sawant, R.M.
Tripathi, S.C.
Singh, A.K.
Gandhi, P.M.
Hubli, R.C.
Suri, A.K.
description A novel extractant, namely, Benzodioxodiamide (BenzoDODA) has been synthesized and evaluated for its extraction behaviour towards plutonium and other elements present in the spent nuclear fuel. High separation factors for plutonium over other elements were observed, indicating the high selectivity of the extractant for plutonium. The extractant is quite promising for the selective separation of plutonium from dissolver solution and various acidic waste streams. A novel extractant, namely, Benzodioxodiamide (BenzoDODA) has been synthesized and evaluated for its extraction behaviour towards plutonium and other elements present in the spent nuclear fuel. High separation factors for plutonium over other elements were observed, indicating the high selectivity of the extractant for plutonium. The extractant is quite promising for the selective separation of plutonium from dissolver solution and various acidic waste streams.
doi_str_mv 10.1016/j.tetlet.2012.07.124
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1873-3581
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source Elsevier ScienceDirect Journals
subjects BenzoDODA
Dissolvers
Extraction
HLW
Liquid–liquid extraction
Plutonium
Pu(IV)
Separation
Spent nuclear fuels
Streams
Tetrahedrons
Wastes
title Bis-(2-ethylhexyl) carbamoyl methoxy phenoxy-bis-(2-ethylhexyl) acetamide [BenzoDODA]—first selective extractant for plutonium(IV) recovery (SEPUR) from acidic media
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