Copper-mediated cyanation of aryl boronic acids using benzyl cyanide

An efficient copper-mediated synthesis of aryl nitriles from aryl boronic acids has been achieved using benzyl cyanide as a user-friendly cyanide source. Various aryl boronic acids underwent the reaction smoothly, affording the corresponding aryl nitriles in moderate to good yields. tert-Butyl hydro...

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Veröffentlicht in:	Tetrahedron 2013-09, Vol.69 (39), p.8400-8404
Hauptverfasser:	Luo, Yan, Wen, Qiaodong, Wu, Zhiyuan, Jin, Jisong, Lu, Ping, Wang, Yanguang
Format:	Artikel
Sprache:	eng
Schlagworte:	Aromatic compounds Benzyl cyanide Boronic acid Copper catalysis Cyanation Cyanides C–H oxidation Nitriles Synthesis Tetrahedrons
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