Shape persistent hybrid dendrimers from benzene and triazole via ‘click chemistry’

Fully aromatic rigid dendrimers have been synthesized at room temperature based on two different ‘click’-reactions: The dendronization was carried out via the copper catalyzed azide–alkyne Huisgen cycloaddition or Diels–Alder cycloaddition, respectively. The feasible combination of both reactions le...

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Veröffentlicht in:Tetrahedron 2014-05, Vol.70 (19), p.3178-3184
Hauptverfasser: Stangenberg, René, Türp, David, Müllen, Klaus
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container_issue 19
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container_title Tetrahedron
container_volume 70
creator Stangenberg, René
Türp, David
Müllen, Klaus
description Fully aromatic rigid dendrimers have been synthesized at room temperature based on two different ‘click’-reactions: The dendronization was carried out via the copper catalyzed azide–alkyne Huisgen cycloaddition or Diels–Alder cycloaddition, respectively. The feasible combination of both reactions leads to dendrimer hybrids. Stiff aromatic dendrimers, whose highly nitrogen containing scaffolds are solely based on interconnected benzene and triazole rings, were created. [Display omitted]
doi_str_mv 10.1016/j.tet.2014.03.037
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source Elsevier ScienceDirect Journals
subjects Benzene
Click chemistry
Copper
Cycloaddition
Dendrimer
Dendrimers
Polyphenylene
Scaffolds
Synthesis
Tetrahedrons
Triazole
Triazoles
title Shape persistent hybrid dendrimers from benzene and triazole via ‘click chemistry’
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